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- W2046301836 abstract "Abstract At has been proposed from experimental studies and in analogy with hydrogen compounds that PsO may be an entity of some importance, or an intermediate, in the reaction of positronium, Ps, with aqueous oxyacid species such as H 2 PO − 4 , HSO − 4 , ClO − 4 , and NO − 3 . This communication explores the stability of PsO and PsS, or [0 − : e + ] and [S − :e + ], respectively, relative to dissociation into Ps and O( 3 P) or S( 3 P) on the basis of restricted Hartree-Fock calculations for the PsO and PsS systems and certain correlation correction arguments. We obtain a reasonable lower estimate of the dissociation energy to Y + Ps of ⪢ −0.47 eV for PsO and ⪢ −0.70 eV for PsS. It is suggested that a modest correlation correction to the positron affinity (PA) of O − would very probably lead to a bound state system for PsO." @default.
- W2046301836 created "2016-06-24" @default.
- W2046301836 creator A5057205576 @default.
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- W2046301836 date "1977-05-01" @default.
- W2046301836 modified "2023-09-24" @default.
- W2046301836 title "Theoretical condiserations regarding the existence of PsO and PsS+" @default.
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- W2046301836 doi "https://doi.org/10.1016/0009-2614(77)85047-1" @default.
- W2046301836 hasPublicationYear "1977" @default.
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