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- W2046304059 abstract "Superoxide ion (O2−) generation in ionic liquids (ILs) has been investigated recently using various types of ILs. Imidazolium based ILs are the most frequently studied ILs. In this work, O2− was generated and analyzed electrochemically using cyclic voltammetry and chronoamperometry techniques from O2 dissolved in 1-butyl-3-methylimidazolium trifluoromethanesulfonate [BMIm][TfO]. Furthermore, O2− was generated chemically by potassium superoxide addition into the same IL. UV/Vis spectrophotometry was utilized for testing the long term stability of the generated O2− and GC/MS was used to investigate the possible reaction between the generated O2− and [BMIm][TfO]. The results showed that O2− was unstable in this IL. The GC/MS results confirmed that O2− has reacted with [BMIm][TfO] producing 1-butyl-3-methyl-2-imidazolone in a high purity and excellent yield. This product and its family are used widely in various applications and have a very important role in pharmacology and chemotherapy." @default.
- W2046304059 created "2016-06-24" @default.
- W2046304059 creator A5006302651 @default.
- W2046304059 creator A5048518270 @default.
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- W2046304059 date "2013-05-01" @default.
- W2046304059 modified "2023-10-08" @default.
- W2046304059 title "An investigation of the reaction between 1-butyl-3-methylimidazolium trifluoromethanesulfonate and superoxide ion" @default.
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- W2046304059 doi "https://doi.org/10.1016/j.molliq.2013.02.001" @default.
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