Matches in SemOpenAlex for { <https://semopenalex.org/work/W2046323457> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W2046323457 abstract "Abstract Allylbenzene ozonide (ABO), a model for polyunsaturated fatty acid (PUFA) ozonides, initiates the autoxidation of methyl linoleate (18∶2 ME) at 37°C under 760 torr of oxygen. This process is inhibited by d‐α‐tocopherol (α‐T) and 2,6‐di‐ ert ‐butyl‐4‐methylphenol (BHT). The autoxidation was followed by the appearance of conjugated diene (CD), as well as by oxygen‐uptake. The rates of autoxidation are proportional to the square root of ABO concentration, implying that the usual free radical autoxidation rate law is obeyed. Activation parameters for the thermal decomposition of ABO were determined under N 2 in the presence of radical scavengers and found to be E a =28.2 ±0.3 kcal mol −1 and log A=13.6±0.2; k d (37°C) is calculated to be (5.1±0.3)×10 −7 sec −1 . Autoxidation data are also reported for ozonides of 18∶2 ME and methyl oleate (18∶1 ME)." @default.
- W2046323457 created "2016-06-24" @default.
- W2046323457 creator A5028985147 @default.
- W2046323457 creator A5058366379 @default.
- W2046323457 creator A5063217667 @default.
- W2046323457 creator A5066531588 @default.
- W2046323457 creator A5070033311 @default.
- W2046323457 date "1989-07-01" @default.
- W2046323457 modified "2023-09-29" @default.
- W2046323457 title "Autoxidation of methyl linoleate initiated by the ozonide of allylbenzene" @default.
- W2046323457 cites W1925954526 @default.
- W2046323457 cites W1969806153 @default.
- W2046323457 cites W1975477855 @default.
- W2046323457 cites W1988987420 @default.
- W2046323457 cites W2011944264 @default.
- W2046323457 cites W2029693479 @default.
- W2046323457 cites W2029748628 @default.
- W2046323457 cites W2032508526 @default.
- W2046323457 cites W2038996888 @default.
- W2046323457 cites W2072210623 @default.
- W2046323457 cites W2074512562 @default.
- W2046323457 cites W2077898467 @default.
- W2046323457 cites W2079298830 @default.
- W2046323457 cites W2085035284 @default.
- W2046323457 cites W2133403539 @default.
- W2046323457 cites W2277085938 @default.
- W2046323457 cites W2321181820 @default.
- W2046323457 cites W2321300414 @default.
- W2046323457 cites W2331138216 @default.
- W2046323457 cites W2333672002 @default.
- W2046323457 cites W2345430251 @default.
- W2046323457 cites W297748149 @default.
- W2046323457 cites W3004913538 @default.
- W2046323457 cites W327938830 @default.
- W2046323457 cites W4249721642 @default.
- W2046323457 doi "https://doi.org/10.1007/bf02535077" @default.
- W2046323457 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/2640562" @default.
- W2046323457 hasPublicationYear "1989" @default.
- W2046323457 type Work @default.
- W2046323457 sameAs 2046323457 @default.
- W2046323457 citedByCount "30" @default.
- W2046323457 countsByYear W20463234572015 @default.
- W2046323457 countsByYear W20463234572017 @default.
- W2046323457 countsByYear W20463234572021 @default.
- W2046323457 countsByYear W20463234572022 @default.
- W2046323457 crossrefType "journal-article" @default.
- W2046323457 hasAuthorship W2046323457A5028985147 @default.
- W2046323457 hasAuthorship W2046323457A5058366379 @default.
- W2046323457 hasAuthorship W2046323457A5063217667 @default.
- W2046323457 hasAuthorship W2046323457A5066531588 @default.
- W2046323457 hasAuthorship W2046323457A5070033311 @default.
- W2046323457 hasConcept C155647269 @default.
- W2046323457 hasConcept C178790620 @default.
- W2046323457 hasConcept C185592680 @default.
- W2046323457 hasConcept C2778283238 @default.
- W2046323457 hasConcept C2779173278 @default.
- W2046323457 hasConcept C37329643 @default.
- W2046323457 hasConcept C540031477 @default.
- W2046323457 hasConcept C75473681 @default.
- W2046323457 hasConceptScore W2046323457C155647269 @default.
- W2046323457 hasConceptScore W2046323457C178790620 @default.
- W2046323457 hasConceptScore W2046323457C185592680 @default.
- W2046323457 hasConceptScore W2046323457C2778283238 @default.
- W2046323457 hasConceptScore W2046323457C2779173278 @default.
- W2046323457 hasConceptScore W2046323457C37329643 @default.
- W2046323457 hasConceptScore W2046323457C540031477 @default.
- W2046323457 hasConceptScore W2046323457C75473681 @default.
- W2046323457 hasIssue "7" @default.
- W2046323457 hasLocation W20463234571 @default.
- W2046323457 hasLocation W20463234572 @default.
- W2046323457 hasOpenAccess W2046323457 @default.
- W2046323457 hasPrimaryLocation W20463234571 @default.
- W2046323457 hasRelatedWork W1986184766 @default.
- W2046323457 hasRelatedWork W2000632154 @default.
- W2046323457 hasRelatedWork W2018893229 @default.
- W2046323457 hasRelatedWork W2021943324 @default.
- W2046323457 hasRelatedWork W2035450648 @default.
- W2046323457 hasRelatedWork W2046323457 @default.
- W2046323457 hasRelatedWork W2065959784 @default.
- W2046323457 hasRelatedWork W2069740325 @default.
- W2046323457 hasRelatedWork W2260282370 @default.
- W2046323457 hasRelatedWork W2464191735 @default.
- W2046323457 hasVolume "24" @default.
- W2046323457 isParatext "false" @default.
- W2046323457 isRetracted "false" @default.
- W2046323457 magId "2046323457" @default.
- W2046323457 workType "article" @default.