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- W2046334517 abstract "The compounds which are discussed in the present review are highly oxidizing Ru(II) complexes, based on various polyazaaromatic ligands, and acting as efficient electron acceptors in the excited state. The photoinduced charge transfer process and the following associated kinetic steps are characterized for the whole series of complexes by quite different techniques and methods. Thus their behaviour in the presence of reductants such as hydroquinone and mononucleotides (guanosine-5′-monophosphate and adenosine-5′-monophosphate) are examined by flash photolysis, spectroelectrochemistry and photoelectrochemistry. It is explained how the light-initiated electron transfer process can be applied for spectral supersensitization of wide band gap SnO2 semiconductor electrodes. Moreover, it is shown that such a knowledge of the behaviour of these photoredox reactions leads to interesting applications of these oxidizing complexes in a biological area, i.e. for the study of nucleic acids. Thus it is illustrated how these compounds can be used as promising photoreagents of DNA. The easy modulation of their size and shape, and their irreversible anchoring on the DNA bases, triggered by the reductive photoelectron transfer process from the guanine bases to the excited complex, allow one to regard these complexes as attractive molecular tools for DNA study and maybe as future possible drugs activatable under visible light." @default.
- W2046334517 created "2016-06-24" @default.
- W2046334517 creator A5032450006 @default.
- W2046334517 creator A5044864288 @default.
- W2046334517 creator A5063556288 @default.
- W2046334517 date "1998-01-01" @default.
- W2046334517 modified "2023-10-12" @default.
- W2046334517 title "Ru(II) polypyridine complexes with a high oxidation power. Comparison between their photoelectrochemistry with transparent SnO2 and their photochemistry with desoxyribonucleic acids" @default.
- W2046334517 cites W17850123 @default.
- W2046334517 cites W1872738104 @default.
- W2046334517 cites W1963687146 @default.
- W2046334517 cites W1965833544 @default.
- W2046334517 cites W1968330562 @default.
- W2046334517 cites W1968455007 @default.
- W2046334517 cites W1968803237 @default.
- W2046334517 cites W1969424089 @default.
- W2046334517 cites W1973493562 @default.
- W2046334517 cites W1973803527 @default.
- W2046334517 cites W1977082053 @default.
- W2046334517 cites W1977158349 @default.
- W2046334517 cites W1980216394 @default.
- W2046334517 cites W1980587715 @default.
- W2046334517 cites W1983223009 @default.
- W2046334517 cites W1986197536 @default.
- W2046334517 cites W1988094249 @default.
- W2046334517 cites W1988830614 @default.
- W2046334517 cites W1989365910 @default.
- W2046334517 cites W1990532251 @default.
- W2046334517 cites W1991163357 @default.
- W2046334517 cites W1991517116 @default.
- W2046334517 cites W1993072684 @default.
- W2046334517 cites W1993157680 @default.
- W2046334517 cites W1993181286 @default.
- W2046334517 cites W1994507938 @default.
- W2046334517 cites W1994646516 @default.
- W2046334517 cites W1995661103 @default.
- W2046334517 cites W1995662921 @default.
- W2046334517 cites W1996650095 @default.
- W2046334517 cites W1998127752 @default.
- W2046334517 cites W1998930615 @default.
- W2046334517 cites W1999888893 @default.
- W2046334517 cites W2000162862 @default.
- W2046334517 cites W2004831725 @default.
- W2046334517 cites W2004919683 @default.
- W2046334517 cites W2005108095 @default.
- W2046334517 cites W2005252051 @default.
- W2046334517 cites W2008528292 @default.
- W2046334517 cites W2013914883 @default.
- W2046334517 cites W2017237805 @default.
- W2046334517 cites W2018641578 @default.
- W2046334517 cites W2018837467 @default.
- W2046334517 cites W2019323854 @default.
- W2046334517 cites W2019434195 @default.
- W2046334517 cites W2021426946 @default.
- W2046334517 cites W2021605740 @default.
- W2046334517 cites W2032012867 @default.
- W2046334517 cites W2033083998 @default.
- W2046334517 cites W2034233680 @default.
- W2046334517 cites W2036947980 @default.
- W2046334517 cites W2037639276 @default.
- W2046334517 cites W2039318684 @default.
- W2046334517 cites W2039805221 @default.
- W2046334517 cites W2041483077 @default.
- W2046334517 cites W2044658463 @default.
- W2046334517 cites W2046415064 @default.
- W2046334517 cites W2046546736 @default.
- W2046334517 cites W2048965873 @default.
- W2046334517 cites W2050278976 @default.
- W2046334517 cites W2053097042 @default.
- W2046334517 cites W2053569495 @default.
- W2046334517 cites W2055069556 @default.
- W2046334517 cites W2055938468 @default.
- W2046334517 cites W2060335449 @default.
- W2046334517 cites W2062716010 @default.
- W2046334517 cites W2062827372 @default.
- W2046334517 cites W2065477405 @default.
- W2046334517 cites W2065497508 @default.
- W2046334517 cites W2069440310 @default.
- W2046334517 cites W2070278984 @default.
- W2046334517 cites W2071064031 @default.
- W2046334517 cites W2072195331 @default.
- W2046334517 cites W2074067031 @default.
- W2046334517 cites W2076967986 @default.
- W2046334517 cites W2077269625 @default.
- W2046334517 cites W2078360753 @default.
- W2046334517 cites W2079745079 @default.
- W2046334517 cites W2080989217 @default.
- W2046334517 cites W2081019235 @default.
- W2046334517 cites W2083355060 @default.
- W2046334517 cites W2083989522 @default.
- W2046334517 cites W2087656054 @default.
- W2046334517 cites W2090872831 @default.
- W2046334517 cites W2092696219 @default.
- W2046334517 cites W2093193719 @default.
- W2046334517 cites W2097860909 @default.
- W2046334517 cites W2099085138 @default.
- W2046334517 cites W2102555920 @default.
- W2046334517 cites W2110357670 @default.