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- W2046338977 abstract "Die Verbindung kristallisiert in der triklinen Raumgruppe P1 mit a = 8,22, b = 8,33, c = 9,745 Å, α = 109,1°, β = 107,4°, γ = 102,9° und 2 Molekülen in der Elementarzelle. Die beiden Molekeln sind über ein Symmetriezentrum unter Bildung eines BS-Vierrings miteinander verknüpft, so daß sich zwei verschieden koordinierte Bor-Atome im Fünfring ergeben. Die Bindungslängen und -winkel an den beiden Bor-Atomen stimmen recht gut mit den für drei- bzw. vierfach koordiniertes Bor bekannten Werten überein. Der Fünfring ist nahezu planar. Crystal arid Molecular Structure of 2,5-Diiodine-3,4-diethyl-1,2,5-thiadiborolene The title compound crystallizes in the triclinic space group P1 with a = 8.22, b = 8.33, c = 9.745 Å, α = 109.1°, β = 107.1°, γ = 102.9° and two molecules per unit cell. The two molecules are associated by a center of symmetry, forming a four-membered B–S ring, which leads to differently coordinated boron atoms in the thiadiborolene ring. The bond lengths and angles for the boron atoms are similar to those known for trigonally and tetrahedrally bonded boron, respectively. The five-membered ring is nearly planar." @default.
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- W2046338977 date "1976-03-01" @default.
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- W2046338977 title "Kristall- und Molek�lstruktur von 2.5-Dijod-3.4-di�thyl-1.2.5-thiadiborolen" @default.
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- W2046338977 doi "https://doi.org/10.1002/zaac.19764200314" @default.
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