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• W2046341013 startingPage "169" @default.
• W2046341013 abstract "Abstract Dicalcium Barium Propionate (DBP) undergoes a first order phase transition at 267 K and a second order one at 204 K. Dicalcium lead propionate (DLP) also shows two phase transitions—a second-order one at 333 K and a first-order one at 191.5 K. The proton second moment (M 2) in the temperature range 160–300 K and the proton spin-lattice relaxation time (T 1) in the temperature range 77–350 K have been measured to study the motion of the propionate ion in relation to the phase transition. In DBF, the M 2 variation with temperature shows two transitions corresponding to the two phase transitions reported. On the other hand the T 1 measurements yield only a single minimum and a slope change at the second-order phase transition temperature. In DLP, the M 2 study yields a transition in the region 180–190 K, near the first-order phase transition, but no M 2 transition at the second-order phase transition, T 1 measurements show a single minimum, as well as a slope change at the second-order phase transition. At the first-order phase transition, T 1 changes smoothly. These observations are discussed in relation to propionate ion dynamics." @default.
• W2046341013 created "2016-06-24" @default.
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• W2046341013 date "1985-09-01" @default.
• W2046341013 modified "2023-10-16" @default.
• W2046341013 title "NMR study of phase transitions in dicalcium barium propionate and dicalcium lead propionate" @default.
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• W2046341013 doi "https://doi.org/10.1080/01411598508209316" @default.
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