FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2046370077> ?p ?o ?g. }

• W2046370077 endingPage "3596" @default.
• W2046370077 startingPage "3591" @default.
• W2046370077 abstract "The solid-state structure of the cationic MeO-Biphep Rh(I) compound [Rh((S)-MeO-Biphep)(P{OMe}3)2)]BF4 (3) has been determined by X-ray diffraction. The four P-donors deviate markedly from square-planar geometry, with the phosphite ligands P2 and P2‘ ca. ±0.61(7) Å from the P1−Rh−P1‘ plane. This distortion resembles that found for PdBr(p-NCC6H4)((S)-MeO-Biphep) (1). Density functional calculations on a series of systematically varied models of 1 reveal three major components to be responsible for the observed distortion from square-planar geometry: (i) attractive aromatic ring π−π interactions, (ii) electronic stabilization of coplanar aromatic rings in pseudo-trans positions, and (iii) P-phenyl and MeO-Biphep-phenyl intraligand repulsive steric interactions. Additional DFT studies on the p-tolyl-Binap analogue of 1, PdBr(p-NCC6H4)((R)-p-Tol-Binap) (2), explain the source of the extremely long Pd−P2 bond distance, 2.437(1) Å, in 2. Despite the structural similarity between 1 and 2, the calculations rationalize the observation of a pronounced distortion from a square-planar geometry in the former that is essentially absent in the latter." @default.
• W2046370077 created "2016-06-24" @default.
• W2046370077 creator A5029026743 @default.
• W2046370077 creator A5032820308 @default.
• W2046370077 creator A5037478989 @default.
• W2046370077 creator A5085139579 @default.
• W2046370077 creator A5087482363 @default.
• W2046370077 date "2000-08-05" @default.
• W2046370077 modified "2023-09-23" @default.
• W2046370077 title "Electronically and Sterically Induced Structural Distortions in Square-Planar d⁸ Complexes" @default.
• W2046370077 cites W1589031564 @default.
• W2046370077 cites W1966781526 @default.
• W2046370077 cites W1972712674 @default.
• W2046370077 cites W1980413534 @default.
• W2046370077 cites W1984251321 @default.
• W2046370077 cites W1985305274 @default.
• W2046370077 cites W2019123141 @default.
• W2046370077 cites W2020114693 @default.
• W2046370077 cites W2022526669 @default.
• W2046370077 cites W2023286727 @default.
• W2046370077 cites W2030976617 @default.
• W2046370077 cites W2051094745 @default.
• W2046370077 cites W2052637367 @default.
• W2046370077 cites W2055230539 @default.
• W2046370077 cites W2064666504 @default.
• W2046370077 cites W2073269712 @default.
• W2046370077 cites W2084952976 @default.
• W2046370077 cites W2086957099 @default.
• W2046370077 cites W2099871009 @default.
• W2046370077 cites W2128179591 @default.
• W2046370077 cites W2949927558 @default.
• W2046370077 cites W3107879085 @default.
• W2046370077 doi "https://doi.org/10.1021/om000466q" @default.
• W2046370077 hasPublicationYear "2000" @default.
• W2046370077 type Work @default.
• W2046370077 sameAs 2046370077 @default.
• W2046370077 citedByCount "19" @default.
• W2046370077 countsByYear W20463700772013 @default.
• W2046370077 countsByYear W20463700772022 @default.
• W2046370077 crossrefType "journal-article" @default.
• W2046370077 hasAuthorship W2046370077A5029026743 @default.
• W2046370077 hasAuthorship W2046370077A5032820308 @default.
• W2046370077 hasAuthorship W2046370077A5037478989 @default.
• W2046370077 hasAuthorship W2046370077A5085139579 @default.
• W2046370077 hasAuthorship W2046370077A5087482363 @default.
• W2046370077 hasConcept C115624301 @default.
• W2046370077 hasConcept C121332964 @default.
• W2046370077 hasConcept C121684516 @default.
• W2046370077 hasConcept C126780896 @default.
• W2046370077 hasConcept C134786449 @default.
• W2046370077 hasConcept C155860418 @default.
• W2046370077 hasConcept C178790620 @default.
• W2046370077 hasConcept C183882617 @default.
• W2046370077 hasConcept C185592680 @default.
• W2046370077 hasConcept C193547582 @default.
• W2046370077 hasConcept C194257627 @default.
• W2046370077 hasConcept C201194858 @default.
• W2046370077 hasConcept C2524010 @default.
• W2046370077 hasConcept C2780378348 @default.
• W2046370077 hasConcept C32909587 @default.
• W2046370077 hasConcept C33923547 @default.
• W2046370077 hasConcept C41008148 @default.
• W2046370077 hasConcept C46362747 @default.
• W2046370077 hasConcept C49040817 @default.
• W2046370077 hasConcept C71240020 @default.
• W2046370077 hasConcept C8010536 @default.
• W2046370077 hasConceptScore W2046370077C115624301 @default.
• W2046370077 hasConceptScore W2046370077C121332964 @default.
• W2046370077 hasConceptScore W2046370077C121684516 @default.
• W2046370077 hasConceptScore W2046370077C126780896 @default.
• W2046370077 hasConceptScore W2046370077C134786449 @default.
• W2046370077 hasConceptScore W2046370077C155860418 @default.
• W2046370077 hasConceptScore W2046370077C178790620 @default.
• W2046370077 hasConceptScore W2046370077C183882617 @default.
• W2046370077 hasConceptScore W2046370077C185592680 @default.
• W2046370077 hasConceptScore W2046370077C193547582 @default.
• W2046370077 hasConceptScore W2046370077C194257627 @default.
• W2046370077 hasConceptScore W2046370077C201194858 @default.
• W2046370077 hasConceptScore W2046370077C2524010 @default.
• W2046370077 hasConceptScore W2046370077C2780378348 @default.
• W2046370077 hasConceptScore W2046370077C32909587 @default.
• W2046370077 hasConceptScore W2046370077C33923547 @default.
• W2046370077 hasConceptScore W2046370077C41008148 @default.
• W2046370077 hasConceptScore W2046370077C46362747 @default.
• W2046370077 hasConceptScore W2046370077C49040817 @default.
• W2046370077 hasConceptScore W2046370077C71240020 @default.
• W2046370077 hasConceptScore W2046370077C8010536 @default.
• W2046370077 hasIssue "18" @default.
• W2046370077 hasLocation W20463700771 @default.
• W2046370077 hasOpenAccess W2046370077 @default.
• W2046370077 hasPrimaryLocation W20463700771 @default.
• W2046370077 hasRelatedWork W1968436507 @default.
• W2046370077 hasRelatedWork W1984056926 @default.
• W2046370077 hasRelatedWork W2001362084 @default.
• W2046370077 hasRelatedWork W2009789088 @default.
• W2046370077 hasRelatedWork W2014017601 @default.
• W2046370077 hasRelatedWork W2051423384 @default.
• W2046370077 hasRelatedWork W2052265098 @default.

• next