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- W2046371922 abstract "The reaction of Na(OSitBu2Me) with CrCl3 yields solid [Cr(OSitBu2Me)3]n (1), which can be crystallized in the presence of excess Na(OSitBu2Me) to yield [Na(THF)][Cr(OSitBu2Me)4] (2). This complex is oxidized to yield Cr(OSitBu2Me)4 (3), a crystalline chromium(IV) siloxide complex that is air- and moisture-stable. Electronic spectroscopic analysis of the absorption spectrum of 3 indicates a particularly weak ligand field (ΔT = 7940 cm–1) and covalent Cr–O bonding. 3 provides the first structural and spectroscopic characterization of a homoleptic chromium(IV) siloxide complex and provides a benchmark for tetrahedral chromium(IV) ions residing in solid oxide lattices." @default.
- W2046371922 created "2016-06-24" @default.
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- W2046371922 date "2013-01-22" @default.
- W2046371922 modified "2023-09-27" @default.
- W2046371922 title "Chromium(IV) Siloxide" @default.
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- W2046371922 doi "https://doi.org/10.1021/ic3023612" @default.
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