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- W2046375790 abstract "Abstract We describe the interaction of cycloserine (Ccs), 4-amino-3-isoxazolidone, with the metal ions palladium(II), platinum(II) and copper(II). A series of complexes of general formula M(Ccs)nX2 (M=Pd and Pt, X=Cl, n=2; M=Pd and Pt, X=Br and I, n=3; M=Cu, X=Cl and Br, n=2) have been prepared and characterized by chemical analysis, infrared and electronic spectra, conductivity data, magnetic susceptibility measurements and isotope exchange (deuteration) experiments. The position and multiplicity of the metal-halide stretching frequencies are discussed and used as a guide to the stereochemistry. The most convincing structural evidence for the complexes is a square-planar stereochemistry for the 1:2 derivatives with terminal ligands and terminal halides, while for the 1:3 complexes we could suggest an octahedral dimeric structure with terminal ligands and both bridging and terminal halides. The assignments for the metal-ligand and metal-halides stretching modes have been made. We have never observed a metal induced ring opening under the present experimental conditions." @default.
- W2046375790 created "2016-06-24" @default.
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- W2046375790 date "1979-04-01" @default.
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- W2046375790 title "METAL ION COORDINATION BY THE ANTIBIOTIC CYCLOSERINE. COMPLEXES OF PALLADIUM (II), PLATINUM (II) AND COPPER (II)" @default.
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- W2046375790 doi "https://doi.org/10.1080/00958977908076516" @default.
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