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- W2046396151 abstract "IR spectra were recorded for HCl and Me2CO in argon matrices and for two-component solid mixtures in various proportions. In a dilute Ar matrix an isolated 1:1 complex, Me2CO···HCl was identified by the xxxs (HCl) at 2392 cm1̄. At higher concentrations in an Ar matrix, and in two-component solid mixtures, in both cases with excess acid, the proton transfer form Me2COH+ ···Cl− was identified by its characteristic xxxs(OH+) band at 2500 cm−1. In the two-component solid mixtures containing an excess of base, a symmetrical hydrogen bond [Me2CO···H···OCMe2] +was identified from the broad absorption in the region 500–1500 cm−1. The experimental results have been rationalized with the aid of CNDO/2 calculations for HCl, Me2CO, and their 1:1 and 2:1 complexes with different geometry." @default.
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- W2046396151 date "1978-01-01" @default.
- W2046396151 modified "2023-10-16" @default.
- W2046396151 title "Infrared studies of Me2CO - HCl Hydrogen bonded compiex in argon matrices and two-component solids" @default.
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- W2046396151 doi "https://doi.org/10.1016/0022-2860(78)87196-8" @default.
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