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• W2046396277 startingPage "3218" @default.
• W2046396277 abstract "New measurements of chain self-diffusion $(D)$ in highly entangled hydrogenated polybutadiene solutions and melts indicate that $Densuremath{sim}{M}^{ensuremath{-}2.3ifmmodepmelsetextpmfi{}0.1}$, where $M$ is the molecular weight. Although these results contradict the widespread belief that in melts $Densuremath{sim}{M}^{ensuremath{-}2.0}$, we demonstrate that in fact the literature data for seven different polymers are consistent with $Densuremath{sim}{M}^{ensuremath{-}2.28ifmmodepmelsetextpmfi{}0.05}$. This result largely removes a recalcitrant discrepancy between the $M$ exponents for $D$ and the viscosity. Important implications for theoretical approaches are also noted." @default.
• W2046396277 created "2016-06-24" @default.
• W2046396277 creator A5021121847 @default.
• W2046396277 date "1999-10-18" @default.
• W2046396277 modified "2023-09-26" @default.
• W2046396277 title "Reconciliation of the Molecular Weight Dependence of Diffusion and Viscosity in Entangled Polymers" @default.
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• W2046396277 doi "https://doi.org/10.1103/physrevlett.83.3218" @default.
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