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- W2046401410 abstract "The crystal form of the salt [{C5H4(CH3)2}2Fe–Hg–Fe{C5H4(CH3)2}2Hg(BF4)2, 1], prepared by a reaction of tetramethyl[2]ferrocenophane and Hg(CN)2 in ethanol containing HBF4, is triclinic, space group , a = 9.315(3), b = 12.823(4), c = 14.108(5) A, α = 106.055(2), β = 100.253(2), γ = 94.460(2)°, Z = 2 and the final R = 0.059 and Rw = 0.072. Two ferrocene moieties are coordinated to the Hg atom from the opposite side, and the previously proposed Fe–Hg–Fe bridged structure has been verified. The structural feature of the cation is found in the conformation of the ferrocene moiety around the Fe–Hg–Fe bond. In order to reduce the steric hindrance between the Hg and ferrocene moieties, each moiety rotates largely with respect to the other (the torsion angle of the Cpcnt–Fe(1)···Fe(2)–Cpcnt is 75(1)° and Cpcnt is defined as the centroid of the Cp-ring). The mean Fe–Hg distance is 2.598(8) A and the Fe–Hg–Fe bond angle is 176.4(1)°. The two C5H4 rings are greatly tilted, the mean tilting angle between them being 3..." @default.
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- W2046401410 date "1998-05-01" @default.
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- W2046401410 title "Molecular Structure of Hg-Bridged Tetramethyl[2]ferrocenophane Salt ([{C<sub>5</sub>H<sub>4</sub>(CH<sub>3</sub>)<sub>2</sub>}<sub>2</sub>Fe–Hg–Fe{C<sub>5</sub>H<sub>4</sub>(CH<sub>3</sub>)<sub>2</sub>}<sub>2</sub>]<sup>2+</sup>(BF<sub>4</sub><sup>−</sup>)<sub>2</sub>) and Related Salts" @default.
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- W2046401410 doi "https://doi.org/10.1246/bcsj.71.1071" @default.
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