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- W2046408088 abstract "The local environments for oxygen in yttrium-containing pyrochlores and fluorites, Y2(B1−xB′x)2O7 (B=Ti, B′=Sn, Zr) are investigated by using solid state 17O MAS NMR spectroscopy. The quadrupolar coupling constants of the I=52 nucleus, 17O are sufficiently small for these ionic oxides, that high-resolution spectra are obtained from the MAS spectra. Different oxygen NMR resonances are observed due to local environments with differing numbers of metal cations (Y3+, Sn4+, Ti4+ and Zr4+), allowing the numbers of different local environments to be quantified and cation mixing to be investigated. Evidence for pyrochlore-like local ordering is detected for Y2Zr2O7, which nominally adopts the fluorite structure." @default.
- W2046408088 created "2016-06-24" @default.
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- W2046408088 date "2003-10-01" @default.
- W2046408088 modified "2023-10-18" @default.
- W2046408088 title "17O MAS NMR study of the oxygen local environments in the anionic conductors Y2(B1−xB′x)2O7(B, B′=Sn, Ti, Zr)" @default.
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- W2046408088 doi "https://doi.org/10.1016/s0022-4596(03)00290-1" @default.
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