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- W2046408974 abstract "NMR and FT-IR Studies of the conformational changes of guanosine and guanosine-5′-monophosphate upon substitution of the H8 of guanine by a heavy, large atom, such as bromine, are presented. The conformational forms, syn, anti, C2′-endo and C3′-endo and gg, gt and tg rotamers of the above molecules are compared to those of their metal (Mg2+ and Pt2+) adducts, where the metal is fixed to the N7 nitrogen atom of guanine. The antitumor activity of cisplatin is discussed with relation to the conformational form and the effect of cisplatin is compared to the effects of the Mg2+ ion and carcinogens." @default.
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- W2046408974 date "1987-08-01" @default.
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- W2046408974 title "NMR and FT-IR conformational studies of 8-substituted guanine nucleosides and nucleotides and their metal adducts and cancer" @default.
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- W2046408974 doi "https://doi.org/10.1016/s0020-1693(00)81166-4" @default.
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