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• W2046451392 abstract "We immobilized hydroquinone through a spacer to polymer grafted on carbon black and achieved a high-surface-area biofuel cell electrode. Quinone compounds are well-known to transfer electrons in the respiratory chain and have been considered prospective mediators in biofuel cells because of their relatively negative redox potentials. Evaluation of three different spacer arms tethering hydroquinone to linear polymers revealed that only the hydrophilic and flexible di(ethylene oxide) spacer made it possible for immobilized hydroquinone to transfer electrons from glucose oxidase (GOD) to an electrode; direct immobilization and an alkyl spacer did not. The electrode comprising hydroquinone immobilized through di(ethylene oxide) spacer to polymer grafted on carbon black transferred electrons from GOD to the electrode. The potential at which an anodic current began to increase was more negative by about 0.2 V than that for a vinylferrocene-mediated electrode, while the increase in the anodic current density was of the same order." @default.
• W2046451392 created "2016-06-24" @default.
• W2046451392 creator A5009868639 @default.
• W2046451392 creator A5020439739 @default.
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• W2046451392 date "2007-08-01" @default.
• W2046451392 modified "2023-10-14" @default.
• W2046451392 title "Immobilization of Hydroquinone through a Spacer to Polymer Grafted on Carbon Black for a High-Surface-Area Biofuel Cell Electrode" @default.
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• W2046451392 doi "https://doi.org/10.1021/jp074334n" @default.
• W2046451392 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17685650" @default.
• W2046451392 hasPublicationYear "2007" @default.
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