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- W2046452989 abstract "The formation and structure of negative ions from iron and nickel carbonyl has been studied in gas-phase collision experiments using both low-energy (≦ 10 eV) electrons and fast (≦40 eV) potassium atoms as projectiles. Dissociative attachment of low-energy electrons to Fe(CO)5 and Ni(CO)4 occurs with a high probability to produce Fe(CO)4− and Ni(CO)3−, respectively. Structure is found in the dissociative attachment cross section for producing Fe(CO)3− and Fe(CO)2− from Fe(CO)5 in the energy region from 3 eV to 6 eV. This structure is attributed to predissociation from an electronically excited state of the Fe(CO)4− ion." @default.
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- W2046452989 date "1976-11-01" @default.
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- W2046452989 title "Formation of gas-phase negative ions in Fe(CO)5 and Ni(CO)4" @default.
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- W2046452989 doi "https://doi.org/10.1016/0020-7381(76)80106-4" @default.
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