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- W2046477896 abstract "Trialkyl trithioarsenites, (RS) 3 As, bearing terminal carboxy (─COOH) or carboxylate (─COO−Na+) or zwitterionic (─CH(NH 3 +)COO−) groups were studied for their ability to be oxidized by octasulfur, S 8 , and by dioxygen. The carboxy-bearing trithioarsenites are not oxidized by S 8 to the corresponding As(V) esters, (RS) 3 As=S, probably because they cannot open the octasulfur ring, but they react with S 8 in the presence of triethylamine, which acts as an activator of S8. The carboxylate-bearing trithioarsenites, however, do react under drastic conditions with S 8 . In both cases colored insoluble solids were obtained which could not be characterized. The carboxy-bearing trithioarsenites are oxidized by air in a hydrocarbon chain-length depended manner, while the carboxylate-bearing trithioarsenites are not, if at all, oxidized by air to arsenic(III) oxide, As 2 O 3 , and disulfide, RSSR. The zwitterion-bearing tris(penicillamine), tris(cysteine), and tris(glutathione) trithioarsenites are air oxidized slower than their corresponding parent thiols and this may be of biochemical significance." @default.
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- W2046477896 date "2006-02-01" @default.
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- W2046477896 title "The Oxidation of Trialkyl Trithioarsenites, (RS)3As, by Octasulfur/Triethylamine and Dioxygen" @default.
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- W2046477896 doi "https://doi.org/10.1080/104265091001092" @default.
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