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- W2046522101 abstract "The hydroformylation of n-butenes to n-pentanal and 2-methylbutanal using PtCl2(cod)/PPh3/SnCl2 as a catalyst precursor was investigated. It was found that three competing processes take place: substrate hydroformylation, isomerization and hydrogenation. The isomerizing behaviour is closely related to the operating temperature: at low temperatures the system does not isomerize, while at higher temperatures it does. The PPh3/Pt molar ratio also plays an important role in determining the isomerizing behaviour and selectivity to linear aldehyde. Selectivity in n-pentanal from 2-butenes in isomerizing conditions reaches 40–70%. 2-Chlorobutane is a typical byproduct of this system; it is obtained by the reaction of n-butenes with HCl produced in the activation phase of the catalyst precursor. Acidity probably plays a key role in catalytic systems operating at T > 100 °C." @default.
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- W2046522101 date "1990-02-01" @default.
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- W2046522101 title "Hydroformylation of linear butenes with the platinum/tin/triphenylphosphine catalytic system part 1" @default.
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- W2046522101 doi "https://doi.org/10.1016/0304-5102(90)85022-a" @default.
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