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- W2046538106 abstract "The preparation and characterisation of square planar cationic rhodium(I) dicarbonyl complexes {[Rh((mim)2CO)(CO)2]+BPh4−] (1),{[Rh((mim)2CH2)(CO)2]+BPh4−} (2) and{[Rh((mBnzim)2CH2)(CO)2]+BPh4−} (3) [mim=N-methylimidazol-2-yl, mBnzim=N-methylbenzimidazol-2-yl] is reported. The carbonyl ligands in 2 and 3 are readily exchanged for triphenylphosphine to form{[Rh((mim)2CH2)(PPh3)2]+BPh4−} (7) and {[Rh((mBnzim)2CH2)(PPh3)2]+BPh4−} (8). Complexes 2 and 3 were characterised by multinuclear NMR spectroscopy as well as by X-ray crystallography. Structural characterisation by X-ray analysis confirmed that complexes 2 and 3 are essentially square planar." @default.
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- W2046538106 date "1999-10-01" @default.
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- W2046538106 title "Rhodium complexes containing bidentate imidazolyl ligands: synthesis and structure" @default.
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- W2046538106 doi "https://doi.org/10.1016/s0022-328x(99)00347-2" @default.
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