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- W2046543305 abstract "Excess molar enthalpies have been measured at 298.15 K for methanol + pyridine, + 2-methylpyridine (α-picoline), and + 2,6-dimethylpyridine (2,6-lutidine), with an isothermal dilution calorimeter. All the mixtures exhibit negative excess enthalpies, the absolute values of which increase in the sequence: pyridine < α-picoline < 2,6-lutidine. The signs and relative magnitudes of thermodynamic excess functions are as follows: HmE < TSmE < GmE < 0. Enthalpies of hydrogen-bond formation between methanol and pyridines are estimated from the present HmEs and the results are discussed in terms of the base strengths of pyridines, specific solvation, and hydrogen bonding." @default.
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- W2046543305 date "1985-10-01" @default.
- W2046543305 modified "2023-09-27" @default.
- W2046543305 title "Excess molar enthalpies of methanol + pyridine, + methylpyridine, and + 2,6-dimethylpyridine" @default.
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- W2046543305 doi "https://doi.org/10.1016/0021-9614(85)90002-3" @default.
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