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- W2046589060 abstract "Rate constants for the radical-radical reactions N + OH → NO + H (1), and O + OH → O2 + H (2) have been measured for the first time by a direct method. In each experiment, a known concentration of N or O atoms is established in a discharge-flow system. OH radicals are then created by flash photolysis of H2O present in the flowing gas, and the disappearance of OH is monitored by time-resolved observations of its resonance fluorescence. The experiments yield K1 = (5.0 = 1.2) × 10−11 cm3 molecule−1 s−1 and k2 = (3.8 = 0.9) × 10−11 cm3 molecule−1 s−1, for the reactions at 298 = 5 K." @default.
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- W2046589060 date "1980-01-01" @default.
- W2046589060 modified "2023-09-25" @default.
- W2046589060 title "Direct rate measurements on the reactions N + OH → NO + H And O + OH → O2 + H" @default.
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- W2046589060 doi "https://doi.org/10.1016/0009-2614(80)80009-1" @default.
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