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- W2046596706 abstract "Abstract This work reports the oxidative electrochemical polymerization of the trans -[RuCl 2 (pmp) 4 ] monomer, where pmp = 3-(pyrrol-1-ylmethyl) pyridine. Its galvanostatic and potentiodynamic electropolymerization produced strongly adhesive and electroactive films on platinum, palladium and optically transparent electrodes. The efficiency of the film formation indicated the existence of a strong correlation between the applied upper-limit value of the potential range applied and the number of cycles. Electrochemical studies show that the redox properties of poly- trans -[RuCl 2 (pmp) 4 ] are very similar to the monomer trans -[RuCl 2 (pmp) 4 ] in solution. Morphology and thickness measurements studies were performed by scanning electron microscopy (SEM). Microprobe X-ray dispersive energy analysis (EDAX) on the polymeric surface has also been carried out." @default.
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- W2046596706 date "1997-10-01" @default.
- W2046596706 modified "2023-09-27" @default.
- W2046596706 title "Oxidative formation of electroactive film from polypyridinyl complexes of ruthenium (II)-containing 3-(pyrrol-1-ylmethyl) pyridine" @default.
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- W2046596706 doi "https://doi.org/10.1016/s0379-6779(97)80339-5" @default.
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