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- W2046610040 abstract "The iron dihydride FeH2(PP3) [PP3 = P(CH2CH2CH2PMe2)3] is fluctional, with the terminal co-ordinated phos-phine groups undergoing intramolecular exchange in addition to the iron-bound hydrides. The exchange kinetics of the metal-bound hydrides was examined using a magnetization inversion–transfer–recovery method, and the activation energy was ca. 64 kJ mol−1 at 260 K. The effect of spin–spin coupling on the magnetization transfer was examined." @default.
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- W2046610040 date "1991-01-01" @default.
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- W2046610040 title "Kinetics of skeletal rearrangement of H2FeP[CH2CH2CH2P(CH3)2]3 by an inversion-transfer-recovery NMR method" @default.
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- W2046610040 doi "https://doi.org/10.1002/mrc.1260290108" @default.
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