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- W2046618583 abstract "We report studies of the collapse of monolayers of cyclolinear poly(organosiloxane)s that consist of six-membered rings joined by oxygen bridges and that contain two phenyl groups per monomer unit. Surface pressure−area isotherms show that these films undergo a stepwise collapse. The organization within the films has been examined at different stages of the collapse process by Brewster-angle microscopy. Films transferred to mica by the Langmuir−Blodgett technique have been imaged by scanning force microscopy. Five fractions of an atactic polymer with molecular weights (MW) ranging from 8900 to 85 000 and one trans-tactic polymer (MW = 8100) have been investigated. Bilayers of the fractions with the highest MW's appear in the form of islands but the bilayers in the other samples have the form of ribbons 50−250 nm wide." @default.
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- W2046618583 date "1999-12-01" @default.
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- W2046618583 title "Stepwise Collapse of Monolayers of Cyclolinear Poly(organosiloxane)s at the Air/Water Interface: A Brewster-Angle Microscopy and Scanning Force Microscopy Study" @default.
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- W2046618583 doi "https://doi.org/10.1021/jp992708+" @default.
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