FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2046647029> ?p ?o ?g. }

• W2046647029 endingPage "933" @default.
• W2046647029 startingPage "933" @default.
• W2046647029 abstract "Pyridylmethylthiourea derivatives coordinate with [(en)2Co(OSO2CF3)2]+ in a tridentate manner resulting in the formation of a hypodentate ethylenediamine ligand. Four ligands were studied: N-(R)phenyl-N′-2-pyridylmethylthiourea (R = H (1a), CH3 (1b), OCH3 (1c)) and N-benzyl-N′-2-pyridylmethylthiourea (2). These bind through the sulfur, a deprotonated exo nitrogen, and the pyridyl nitrogen atoms forming four and five-membered rings, respectively. The ligand also coordinates in a bidentate manner through the sulfur and deprotonated endo or exo nitrogen atoms, forming two additional coordination isomers. The solid state structure (X-ray) of one of the bidentate isomers of Co-1b2+ (endo isomer) shows that the coordinated thiourea sulfur induces a structural trans effect of 0.035 Å on the trans Co–N bond while that of the tridentate isomer of Co-1a3+ confirms the coordination mode of the ligand and the presence of a protonated hypodentate ethylenediamine ligand as suggested by 1H and 13C NMR spectroscopy." @default.
• W2046647029 created "2016-06-24" @default.
• W2046647029 creator A5001875736 @default.
• W2046647029 creator A5007928854 @default.
• W2046647029 creator A5011440576 @default.
• W2046647029 creator A5026256638 @default.
• W2046647029 creator A5026825816 @default.
• W2046647029 creator A5029259654 @default.
• W2046647029 creator A5040305041 @default.
• W2046647029 creator A5042379707 @default.
• W2046647029 creator A5057060869 @default.
• W2046647029 date "2014-01-01" @default.
• W2046647029 modified "2023-09-23" @default.
• W2046647029 title "Reaction of 2-Pyridylmethylthiourea Derivatives with [(en)2Co(OSO2CF3)2]+ Induces Hypodentate Coordination of an Ethylenediamine Ligand" @default.
• W2046647029 cites W1589168868 @default.
• W2046647029 cites W1972835461 @default.
• W2046647029 cites W1996043560 @default.
• W2046647029 cites W1999129981 @default.
• W2046647029 cites W2007292555 @default.
• W2046647029 cites W2027449947 @default.
• W2046647029 cites W2029193207 @default.
• W2046647029 cites W2032800199 @default.
• W2046647029 cites W2040712265 @default.
• W2046647029 cites W2042680912 @default.
• W2046647029 cites W2047553979 @default.
• W2046647029 cites W2048797113 @default.
• W2046647029 cites W2048831515 @default.
• W2046647029 cites W2065586872 @default.
• W2046647029 cites W2072470772 @default.
• W2046647029 cites W2092828884 @default.
• W2046647029 cites W2131350133 @default.
• W2046647029 cites W2160124155 @default.
• W2046647029 cites W2166689829 @default.
• W2046647029 cites W3135936131 @default.
• W2046647029 cites W3137153409 @default.
• W2046647029 cites W4246229282 @default.
• W2046647029 cites W4256289503 @default.
• W2046647029 doi "https://doi.org/10.1071/ch14029" @default.
• W2046647029 hasPublicationYear "2014" @default.
• W2046647029 type Work @default.
• W2046647029 sameAs 2046647029 @default.
• W2046647029 citedByCount "1" @default.
• W2046647029 countsByYear W20466470292017 @default.
• W2046647029 crossrefType "journal-article" @default.
• W2046647029 hasAuthorship W2046647029A5001875736 @default.
• W2046647029 hasAuthorship W2046647029A5007928854 @default.
• W2046647029 hasAuthorship W2046647029A5011440576 @default.
• W2046647029 hasAuthorship W2046647029A5026256638 @default.
• W2046647029 hasAuthorship W2046647029A5026825816 @default.
• W2046647029 hasAuthorship W2046647029A5029259654 @default.
• W2046647029 hasAuthorship W2046647029A5040305041 @default.
• W2046647029 hasAuthorship W2046647029A5042379707 @default.
• W2046647029 hasAuthorship W2046647029A5057060869 @default.
• W2046647029 hasConcept C115624301 @default.
• W2046647029 hasConcept C116569031 @default.
• W2046647029 hasConcept C118629725 @default.
• W2046647029 hasConcept C145148216 @default.
• W2046647029 hasConcept C155647269 @default.
• W2046647029 hasConcept C170493617 @default.
• W2046647029 hasConcept C178516000 @default.
• W2046647029 hasConcept C178790620 @default.
• W2046647029 hasConcept C185592680 @default.
• W2046647029 hasConcept C188027245 @default.
• W2046647029 hasConcept C2780728571 @default.
• W2046647029 hasConcept C2780871995 @default.
• W2046647029 hasConcept C30095370 @default.
• W2046647029 hasConcept C544153396 @default.
• W2046647029 hasConcept C55493867 @default.
• W2046647029 hasConcept C66974803 @default.
• W2046647029 hasConcept C68913812 @default.
• W2046647029 hasConcept C71240020 @default.
• W2046647029 hasConcept C8010536 @default.
• W2046647029 hasConceptScore W2046647029C115624301 @default.
• W2046647029 hasConceptScore W2046647029C116569031 @default.
• W2046647029 hasConceptScore W2046647029C118629725 @default.
• W2046647029 hasConceptScore W2046647029C145148216 @default.
• W2046647029 hasConceptScore W2046647029C155647269 @default.
• W2046647029 hasConceptScore W2046647029C170493617 @default.
• W2046647029 hasConceptScore W2046647029C178516000 @default.
• W2046647029 hasConceptScore W2046647029C178790620 @default.
• W2046647029 hasConceptScore W2046647029C185592680 @default.
• W2046647029 hasConceptScore W2046647029C188027245 @default.
• W2046647029 hasConceptScore W2046647029C2780728571 @default.
• W2046647029 hasConceptScore W2046647029C2780871995 @default.
• W2046647029 hasConceptScore W2046647029C30095370 @default.
• W2046647029 hasConceptScore W2046647029C544153396 @default.
• W2046647029 hasConceptScore W2046647029C55493867 @default.
• W2046647029 hasConceptScore W2046647029C66974803 @default.
• W2046647029 hasConceptScore W2046647029C68913812 @default.
• W2046647029 hasConceptScore W2046647029C71240020 @default.
• W2046647029 hasConceptScore W2046647029C8010536 @default.
• W2046647029 hasIssue "6" @default.
• W2046647029 hasLocation W20466470291 @default.
• W2046647029 hasOpenAccess W2046647029 @default.
• W2046647029 hasPrimaryLocation W20466470291 @default.
• W2046647029 hasRelatedWork W1983729491 @default.
• W2046647029 hasRelatedWork W2046399046 @default.
• W2046647029 hasRelatedWork W2046647029 @default.

• next