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- W2046670308 abstract "When aqueous solutions of macromolecules are placed in a square, pulsed, orienting electric field they frequently become dichroic and birefrigent. By following the rise of the optical anisotropy as a function of time after application of the pulse one can frequently distinguish between permanent and induced dipole orientation modes. Occasionally, molecules which for symmetry or other reasons are known to have no permanent dipole moment mimic permanent moment orientation. A possible explanation for this phenomenon is that the induced dipole is time dependent. Here we present a formal solution to the rotary diffusion equation for a molecule subjected to a time dependent torque due to an induced dipole mechanism. A new method of solution which can have broad application has been employed. The results are seen to be a viable explanation for the subject in question." @default.
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- W2046670308 date "1978-04-15" @default.
- W2046670308 modified "2023-10-18" @default.
- W2046670308 title "A solution to the rotational diffusion equation to describe molecular orientation due to a time dependent torque" @default.
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- W2046670308 doi "https://doi.org/10.1063/1.436250" @default.
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