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- W2046736258 abstract "The ESR and ENDOR spectra were observed for the 2,6-di-t-butyl-4-cyclopropylphenoxyl radical. The assignments of the proton hyperfine coupling constants were confirmed with reference to those of the 2,6-di-t-butyl-4-methyl- and 4-(1-deuteriocyclopropyl)phenoxyl radicals. The β-proton hyperfine coupling constant for the cyclopropyl group and its temperature dependence were precisely determined. Of particular interest is the fact that the observed cyclopropyl β-proton splitting is smaller than the γ-proton splittings (A4β:0.72, A4γ1:0.83, A4γ2: 1.44 G at −70 °C). Based on the modified cos2θ rule, A4β=(1.85⟨cos2θ⟩−0.10)×A4Me, where the conjugative interaction between the π-system and the cyclopropyl pseudo π-orbital was incorporated, as proposed by Hudson and Bauld, the β-proton splitting was evaluated. The magnitude of the β-proton splitting and its temperature dependence were interpreted in terms of the restricted rotation of the cyclopropyl group in a two-fold potential; the stable conformation was the bi..." @default.
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- W2046736258 date "1980-07-01" @default.
- W2046736258 modified "2023-10-16" @default.
- W2046736258 title "An ENDOR Study of the Hindered Internal Rotation of the Cyclopropyl Group in the 2,6-Di-<i>t</i>-butyl-4-cyclopropylphenoxyl Radical" @default.
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- W2046736258 doi "https://doi.org/10.1246/bcsj.53.1853" @default.
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