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- W2046741208 abstract "A family of η5-CpFe(CO)2-substituted closo-carboranes was synthesized and characterized, including cyclic voltammetry measurements. Like the previously reported bimetallic compound 1,12-[η5-CpFe(CO)2]2-1,12-C2B10H10 (8), 1,10-[η5-CpFe(CO)2]2-1,10-C2B8H8 (9) produces two dissimilar and irreversible one-electron oxidations within the same range, suggesting that it also exhibits through-cage electronic communication between iron centers. Structures determined by X-ray diffraction studies are reported for 1-[η5-CpFe(PPh3)(CO)]-1,12-C2B10H11 (5), 1,12-[η5-CpFe(CO)2]2-1,12-C2B10H10 (8), and 1,10-[η5-CpFe(CO)2]2-1,10-C2B8H8 (9)." @default.
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- W2046741208 date "2004-01-03" @default.
- W2046741208 modified "2023-09-27" @default.
- W2046741208 title "Metal−Metal Communication through Carborane Cages Supporting Electroactive [η<sup>5</sup>-CpFe(CO)<sub>2</sub>] Substituents" @default.
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- W2046741208 doi "https://doi.org/10.1021/om030514h" @default.
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