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- W2046782034 abstract "13C chemical shifts in CDCI3 of 65 compounds, divided into several series, containing a substituted phenyl ring at the imino (N2) nitrogen atom of the amidine group are reported. Additivity parameters (SCS) of the substituted aminomethyleneamino group [R2NC(R′)N-] for the prediction of the chemical shifts of the N2-phenyl carbon atoms in formamidines, acetamidines and guanidines are derived. The SCS obtained can be used for the determination of the configuration at the CN bond, and for the assignments of the chemical shifts in tautomeric forms of N-phenyl-formamidines, -acetamidines and -guanidines. The chemical shifts of the amidine carbon atom depend on the substitutents on the phenyl rings of both nitrogen atoms." @default.
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- W2046782034 date "1986-01-01" @default.
- W2046782034 modified "2023-10-13" @default.
- W2046782034 title "Amidines. XVII—substituent-induced chemical shifts in13C NMR spectra of N2-phenyl-formamidines, -acetamidines and -guanidines" @default.
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- W2046782034 doi "https://doi.org/10.1002/mrc.1260240105" @default.
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