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- W2046804603 abstract "A triptycene-based bis(benzoxazole) diacid ligand H22L2Ph4Ph4 bearing sterically encumbering groups was synthesized. Treatment of H22L2Ph4Ph4 with Fe(OTf)3 afforded a C2-symmetric trinuclear iron(III) complex, [NaFe3(L2Ph4Ph4Ph4)2(μ3-O)(μ-O2CCPh3)2(H2O)3](OTf)2 (8). The triiron core of this complex adopts the well known “basic iron acetate” structure where the heteroleptic carboxylates, comprising two Ph3CCO2− and two (L2Ph4Ph4Ph4)2− ligands, donate the six carboxylate bridges. The (L2Ph4Ph4Ph4)2− ligand undergoes only minor conformational changes upon formation of the complex." @default.
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- W2046804603 date "2012-01-01" @default.
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- W2046804603 title "A C2-symmetric, basic Fe(iii) carboxylate complex derived from a novel triptycene-based chelating carboxylate ligand" @default.
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- W2046804603 doi "https://doi.org/10.1039/c2dt31260c" @default.
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