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- W2046857213 abstract "Abstract Two new equations have been derived to treat the IR data from the monomer-dimer self-association. Equation (9), in the text, is to regress the integrated absorbances of the monomer bands to determine the molar absorptivity of the monomer band, ε m , and the dimerization constant, K . Equation (13), in the text, is to regress those of dimer band to obtain the molar absorptivity of the dimer band, ε d , and dimerization constant K . The self-association in the dilute solution of 2,2-dimethyl-3-ethyl-3-pentanol in carbon disulfide at different temperatures has been used as an example to demonstrate the usage of these two equations. The discrepancy between the values of K at the same temperature determined either from the monomer band or from the dimer band can be used as a criterion for the goodness of determination. The standard enthalpy and entropy of dimerization have also been obtained via a van’t Hoff plot from the data of K at different temperatures. The advantages of this new approach have also been discussed." @default.
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- W2046857213 date "2004-02-01" @default.
- W2046857213 modified "2023-10-17" @default.
- W2046857213 title "New Method to Analyse IR-Studies of Monomer-Dimer Self-Association: 2,2-Dimethyl-3-Ethyl-3-Pentanol in Carbon Disulfide as an Example" @default.
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- W2046857213 doi "https://doi.org/10.1524/zpch.218.2.231.25921" @default.
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