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- W2046896514 abstract "Padé approximants are applied to improve the convergence of various perturbation expansions for the energy of a ground-state hydrogen atom interacting with a proton. It is observed that the convergence defects of the Rayleigh—Schrödinger (RS) polarization and symmetrized RS polarization expansions are not removed by the application of the Padé procedure. On the other hand. Padé approximants for the Murrell—Shaw—Musher—Amos expansion exhibit excellent convergence to the exact energy, despite the divergence of the original series for the antisymmetric 2pαu state. For the perturbation formalisms employing stronger symmetry, forcing the convergence of Padé approximants turns out to be much faster than the convergence of the corresponding perturbation expansions." @default.
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- W2046896514 date "1979-02-01" @default.
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- W2046896514 title "Padé approximants and the convergence problem in the perturbation theory of intermolecular interactions" @default.
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- W2046896514 doi "https://doi.org/10.1016/0009-2614(79)80670-3" @default.
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