Matches in SemOpenAlex for { <https://semopenalex.org/work/W2046909309> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W2046909309 endingPage "619" @default.
- W2046909309 startingPage "613" @default.
- W2046909309 abstract "The overall rate constants of the reactions of NO with hydroxy- and chloroalkylperoxy radicals, derived from the OH- and Cl-initiated oxidation of methacrolein and methyl vinyl ketone, respectively, were directly determined for the first time using the turbulent-flow technique and pseudo-first-order kinetics conditions with high-pressure chemical ionization mass spectrometry for the direct detection of peroxy radical reactants. The individual 100 Torr, 298 K hydroxyalkylperoxy + NO rate constants for the methacrolein [(0.93 ± 0.12) (2σ) × 10-11 cm3 molecule-1 s-1] and methyl vinyl ketone [(0.84 ± 0.10) × 10-11 cm3 molecule-1 s-1] systems were found to be identical within the 95% confidence interval associated with each separate measurement, as were the chloroalkylperoxy + NO rate constants for both methacrolein [(1.17 ± 0.11) × 10-11 cm3 molecule-1 s-1] and methyl vinyl ketone [(1.14 ± 0.14) × 10-11 cm3 molecule-1 s-1]. However, the difference in the rate constants between the hydroxyperoxy + NO and chloroalkylperoxy + NO systems was found to be statistically significant, with the chloroalkylperoxy + NO rate constants about 30% higher than the corresponding hydroxyalkylperoxy + NO rate constants. This substitutent effect was rationalized via a frontier molecular orbital model approach." @default.
- W2046909309 created "2016-06-24" @default.
- W2046909309 creator A5060086549 @default.
- W2046909309 creator A5074384232 @default.
- W2046909309 date "2007-01-04" @default.
- W2046909309 modified "2023-09-27" @default.
- W2046909309 title "Overall Rate Constant Measurements of the Reaction of Hydroxy- and Chloroalkylperoxy Radicals Derived from Methacrolein and Methyl Vinyl Ketone with Nitric Oxide" @default.
- W2046909309 cites W1593655292 @default.
- W2046909309 cites W1980124845 @default.
- W2046909309 cites W1989606456 @default.
- W2046909309 cites W1993517366 @default.
- W2046909309 cites W2009806352 @default.
- W2046909309 cites W2021851614 @default.
- W2046909309 cites W2043426262 @default.
- W2046909309 cites W2049357394 @default.
- W2046909309 cites W2053190336 @default.
- W2046909309 cites W2055117363 @default.
- W2046909309 cites W2069192267 @default.
- W2046909309 cites W2086828965 @default.
- W2046909309 cites W2089584265 @default.
- W2046909309 cites W2115140085 @default.
- W2046909309 cites W2124173165 @default.
- W2046909309 cites W2136938528 @default.
- W2046909309 cites W2142110737 @default.
- W2046909309 cites W2155255257 @default.
- W2046909309 cites W2162875738 @default.
- W2046909309 cites W2076452970 @default.
- W2046909309 doi "https://doi.org/10.1021/jp0665574" @default.
- W2046909309 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17249751" @default.
- W2046909309 hasPublicationYear "2007" @default.
- W2046909309 type Work @default.
- W2046909309 sameAs 2046909309 @default.
- W2046909309 citedByCount "4" @default.
- W2046909309 countsByYear W20469093092019 @default.
- W2046909309 countsByYear W20469093092021 @default.
- W2046909309 crossrefType "journal-article" @default.
- W2046909309 hasAuthorship W2046909309A5060086549 @default.
- W2046909309 hasAuthorship W2046909309A5074384232 @default.
- W2046909309 hasConcept C121332964 @default.
- W2046909309 hasConcept C139066938 @default.
- W2046909309 hasConcept C13934619 @default.
- W2046909309 hasConcept C147789679 @default.
- W2046909309 hasConcept C148898269 @default.
- W2046909309 hasConcept C161790260 @default.
- W2046909309 hasConcept C178790620 @default.
- W2046909309 hasConcept C185592680 @default.
- W2046909309 hasConcept C2775968528 @default.
- W2046909309 hasConcept C2776753869 @default.
- W2046909309 hasConcept C2777738585 @default.
- W2046909309 hasConcept C2780115832 @default.
- W2046909309 hasConcept C2781213060 @default.
- W2046909309 hasConcept C32909587 @default.
- W2046909309 hasConcept C44228677 @default.
- W2046909309 hasConcept C521977710 @default.
- W2046909309 hasConcept C62520636 @default.
- W2046909309 hasConcept C75473681 @default.
- W2046909309 hasConcept C93391505 @default.
- W2046909309 hasConceptScore W2046909309C121332964 @default.
- W2046909309 hasConceptScore W2046909309C139066938 @default.
- W2046909309 hasConceptScore W2046909309C13934619 @default.
- W2046909309 hasConceptScore W2046909309C147789679 @default.
- W2046909309 hasConceptScore W2046909309C148898269 @default.
- W2046909309 hasConceptScore W2046909309C161790260 @default.
- W2046909309 hasConceptScore W2046909309C178790620 @default.
- W2046909309 hasConceptScore W2046909309C185592680 @default.
- W2046909309 hasConceptScore W2046909309C2775968528 @default.
- W2046909309 hasConceptScore W2046909309C2776753869 @default.
- W2046909309 hasConceptScore W2046909309C2777738585 @default.
- W2046909309 hasConceptScore W2046909309C2780115832 @default.
- W2046909309 hasConceptScore W2046909309C2781213060 @default.
- W2046909309 hasConceptScore W2046909309C32909587 @default.
- W2046909309 hasConceptScore W2046909309C44228677 @default.
- W2046909309 hasConceptScore W2046909309C521977710 @default.
- W2046909309 hasConceptScore W2046909309C62520636 @default.
- W2046909309 hasConceptScore W2046909309C75473681 @default.
- W2046909309 hasConceptScore W2046909309C93391505 @default.
- W2046909309 hasIssue "4" @default.
- W2046909309 hasLocation W20469093091 @default.
- W2046909309 hasLocation W20469093092 @default.
- W2046909309 hasOpenAccess W2046909309 @default.
- W2046909309 hasPrimaryLocation W20469093091 @default.
- W2046909309 hasRelatedWork W1972896529 @default.
- W2046909309 hasRelatedWork W1991773596 @default.
- W2046909309 hasRelatedWork W1999787758 @default.
- W2046909309 hasRelatedWork W2046909309 @default.
- W2046909309 hasRelatedWork W2053268433 @default.
- W2046909309 hasRelatedWork W2065761058 @default.
- W2046909309 hasRelatedWork W2068046191 @default.
- W2046909309 hasRelatedWork W2163721691 @default.
- W2046909309 hasRelatedWork W2354468303 @default.
- W2046909309 hasRelatedWork W2952405019 @default.
- W2046909309 hasVolume "111" @default.
- W2046909309 isParatext "false" @default.
- W2046909309 isRetracted "false" @default.
- W2046909309 magId "2046909309" @default.
- W2046909309 workType "article" @default.