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- W2046954384 abstract "The influence of Pr on the superconductivity in copper oxides is argued to depend critically on the energy difference between the Fermi energy EF and the energy Ef of the Pr3+: 4f2 level. With a small fF−Ef, hybridization between Pr-4f and O-2p orbitals transforms the itinerant holes of the p-type superconductors into small polarons, which suppresses Tc. With a large EF−Ef, any such hybridization is too small to change the itinerant character of the mobile holes, and Pr has no more influence on Tc than do the other trivalent rare earths. Comparisons of the influence of Pr on the transition temperature Tc have been made for several systems. In each case, Pr3+ ions occupy sites having four oxygen atoms of a CuO2 sheet as nearest neighbors, and p-type superconductivity is suppressed by Pr only where the sum of the formal positive charge Q per formula unit at the planes adjacent to a CuO2 sheet exceed a critical value. We argue that changes in the local electric field at a Cu atom of the CuO2 sheets lowers EF relative to Ef with increasing Q." @default.
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- W2046954384 date "1989-12-01" @default.
- W2046954384 modified "2023-10-01" @default.
- W2046954384 title "Role of internal electric field on suppression of superconductivity by Pr in copper oxides" @default.
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- W2046954384 doi "https://doi.org/10.1016/0921-4534(89)90392-4" @default.
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