Matches in SemOpenAlex for { <https://semopenalex.org/work/W2046981457> ?p ?o ?g. }
- W2046981457 endingPage "72" @default.
- W2046981457 startingPage "66" @default.
- W2046981457 abstract "It is shown that circularly polarized light produces enantiomeric excesses, above 30%, of twisted nanoribbons self-assembled from racemic dispersions of CdTe nanoparticles. The high optical and chemical activity of nanoparticles (NPs) signifies the possibility of converting the spin angular momenta of photons into structural changes in matter. Here, we demonstrate that illumination of dispersions of racemic CdTe NPs with right- (left-)handed circularly polarized light (CPL) induces the formation of right- (left-)handed twisted nanoribbons with an enantiomeric excess exceeding 30%, which is ∼10 times higher than that of typical CPL-induced reactions. Linearly polarized light or dark conditions led instead to straight nanoribbons. CPL ‘templating’ of NP assemblies is based on the enantio-selective photoactivation of chiral NPs and clusters, followed by their photooxidation and self-assembly into nanoribbons with specific helicity as a result of chirality-sensitive interactions between the NPs. The ability of NPs to retain the polarization information of incident photons should open pathways for the synthesis of chiral photonic materials and allow a better understanding of the origins of biomolecular homochirality." @default.
- W2046981457 created "2016-06-24" @default.
- W2046981457 creator A5009387019 @default.
- W2046981457 creator A5009551001 @default.
- W2046981457 creator A5011944069 @default.
- W2046981457 creator A5018927786 @default.
- W2046981457 creator A5024398640 @default.
- W2046981457 creator A5024800825 @default.
- W2046981457 creator A5024907126 @default.
- W2046981457 creator A5029247141 @default.
- W2046981457 creator A5029359120 @default.
- W2046981457 creator A5031806835 @default.
- W2046981457 creator A5037894959 @default.
- W2046981457 creator A5046576744 @default.
- W2046981457 creator A5048080833 @default.
- W2046981457 creator A5054433421 @default.
- W2046981457 creator A5080502670 @default.
- W2046981457 creator A5083242280 @default.
- W2046981457 date "2014-11-17" @default.
- W2046981457 modified "2023-10-10" @default.
- W2046981457 title "Chiral templating of self-assembling nanostructures by circularly polarized light" @default.
- W2046981457 cites W1980060032 @default.
- W2046981457 cites W1995575412 @default.
- W2046981457 cites W2004600953 @default.
- W2046981457 cites W2005867509 @default.
- W2046981457 cites W2007151621 @default.
- W2046981457 cites W2007855820 @default.
- W2046981457 cites W2013865111 @default.
- W2046981457 cites W2014678552 @default.
- W2046981457 cites W2016977479 @default.
- W2046981457 cites W2018509436 @default.
- W2046981457 cites W2019269997 @default.
- W2046981457 cites W2027027985 @default.
- W2046981457 cites W2049721533 @default.
- W2046981457 cites W2053559173 @default.
- W2046981457 cites W2054105606 @default.
- W2046981457 cites W2062648029 @default.
- W2046981457 cites W2064371338 @default.
- W2046981457 cites W2070745028 @default.
- W2046981457 cites W2074084170 @default.
- W2046981457 cites W2082097221 @default.
- W2046981457 cites W2095188021 @default.
- W2046981457 cites W2097002933 @default.
- W2046981457 cites W2110557476 @default.
- W2046981457 cites W2116346346 @default.
- W2046981457 cites W2156660740 @default.
- W2046981457 cites W2161812676 @default.
- W2046981457 cites W2172249654 @default.
- W2046981457 cites W2316462234 @default.
- W2046981457 cites W2319159996 @default.
- W2046981457 cites W2743523595 @default.
- W2046981457 cites W3099881660 @default.
- W2046981457 doi "https://doi.org/10.1038/nmat4125" @default.
- W2046981457 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4387888" @default.
- W2046981457 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25401922" @default.
- W2046981457 hasPublicationYear "2014" @default.
- W2046981457 type Work @default.
- W2046981457 sameAs 2046981457 @default.
- W2046981457 citedByCount "312" @default.
- W2046981457 countsByYear W20469814572014 @default.
- W2046981457 countsByYear W20469814572015 @default.
- W2046981457 countsByYear W20469814572016 @default.
- W2046981457 countsByYear W20469814572017 @default.
- W2046981457 countsByYear W20469814572018 @default.
- W2046981457 countsByYear W20469814572019 @default.
- W2046981457 countsByYear W20469814572020 @default.
- W2046981457 countsByYear W20469814572021 @default.
- W2046981457 countsByYear W20469814572022 @default.
- W2046981457 countsByYear W20469814572023 @default.
- W2046981457 crossrefType "journal-article" @default.
- W2046981457 hasAuthorship W2046981457A5009387019 @default.
- W2046981457 hasAuthorship W2046981457A5009551001 @default.
- W2046981457 hasAuthorship W2046981457A5011944069 @default.
- W2046981457 hasAuthorship W2046981457A5018927786 @default.
- W2046981457 hasAuthorship W2046981457A5024398640 @default.
- W2046981457 hasAuthorship W2046981457A5024800825 @default.
- W2046981457 hasAuthorship W2046981457A5024907126 @default.
- W2046981457 hasAuthorship W2046981457A5029247141 @default.
- W2046981457 hasAuthorship W2046981457A5029359120 @default.
- W2046981457 hasAuthorship W2046981457A5031806835 @default.
- W2046981457 hasAuthorship W2046981457A5037894959 @default.
- W2046981457 hasAuthorship W2046981457A5046576744 @default.
- W2046981457 hasAuthorship W2046981457A5048080833 @default.
- W2046981457 hasAuthorship W2046981457A5054433421 @default.
- W2046981457 hasAuthorship W2046981457A5080502670 @default.
- W2046981457 hasAuthorship W2046981457A5083242280 @default.
- W2046981457 hasBestOaLocation W20469814572 @default.
- W2046981457 hasConcept C109214941 @default.
- W2046981457 hasConcept C120665830 @default.
- W2046981457 hasConcept C121332964 @default.
- W2046981457 hasConcept C123657345 @default.
- W2046981457 hasConcept C124668440 @default.
- W2046981457 hasConcept C146888428 @default.
- W2046981457 hasConcept C147789679 @default.
- W2046981457 hasConcept C153201621 @default.
- W2046981457 hasConcept C155672457 @default.
- W2046981457 hasConcept C159317903 @default.
- W2046981457 hasConcept C159467904 @default.