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- W2046989211 abstract "The MeCOCH2CMe2 ligand in X3SnCMe2CH2COMe (2; X = halide) acts as a C,O-chelating group both in the solid state and in non-coordinating solutions. The intramolecular SnO bond lengths in trigonal bipyramidal 2 (X = Cl and I), as determined by X-ray crystallography, indicate that the stronger interaction occurs in 2 X = Cl. Comparisons with the SnO bond lengths in the estertin trihalides, X3SnCH2CH2CO2R (1; R = Me), suggest that the latter form stronger chelates than do 2. In chlorocarbon solution, 2 (X = Cl, I) undergoes exchange reactions, as shown by NMR spectra, to give all possible halide derivatives, ∑(ClnI3−nSnCMe2CH2COMe) (n = 0–3). Various ab initio calculations on 2 and X3SnCH2CH2COMe (3) have been carried out. Comparisons of the theoretical and experimental structures of 2 for X = Cl or I are reported. Copyright © 2005 John Wiley & Sons, Ltd." @default.
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- W2046989211 date "2005-01-01" @default.
- W2046989211 modified "2023-09-24" @default.
- W2046989211 title "Experimental andab initio structural study of the ketotin compounds, X3SnCR2CH2COMe: crystal structures of X3SnCMe2CH2COMe (X = Cl and I)" @default.
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- W2046989211 doi "https://doi.org/10.1002/aoc.852" @default.
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