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- W2047008811 abstract "The infrared and Raman spectra of the hydroxides of rubidium and cesium — RbOH o.-rh. (95 K), RbOH mon. I(300 K), CsOH o.-rh. I (95 K), and CsOH o.-rh. II (300 K), and deuterated and isotopically dilute samples — were recorded in the range from 4000-200 cm−1. The spectra exhibit the following main features; (i) hydrogen bonds in both low-temperature modifications despite the large O⋯O bond lengths of &>; 320 pm, due to the great hydrogen bond acceptors, (ii) unusually large halfwidths and splittings (∼50 cm−1 of the OH stretching modes in the IR and Raman spectra of the room-temperature forms, undoubtedly caused by thermally activated reorientation of the non-H-bonded OH− ions, (iii) different OD frequencies of isotopically dilute samples (RbOH mon. I and CsOH o.-rh. II) in the IR and Raman spectra, not found so far for other compounds." @default.
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- W2047008811 date "1986-07-01" @default.
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- W2047008811 title "Hydrogen bonds and dynamic disorder in solid hydroxides, infrared and Raman studies on polymorphic RbOH and CsOH" @default.
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- W2047008811 doi "https://doi.org/10.1016/0022-2860(86)85031-1" @default.
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