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- W2047019898 abstract "Two new empirical methods lead to a quantification of polarisability-derived stabilisation of charge in molecules. These take account of the all-important attentuation of substituent influence as it is further from the charged center. The first is derived from a formula for calculating mean molecular polarisabilities and also takes account of heteroatom substitution. A simple bond-counting procedure is an alternative for unsubstituted alkyl groups. The value of these two models is shown with studies on Cl and Ge ESCA/Auger spectral data, nitrogen 1s binding energy shifts, and with data on the gas phase proton affinities of alkyl substituted amines." @default.
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- W2047019898 date "1984-01-01" @default.
- W2047019898 modified "2023-10-16" @default.
- W2047019898 title "Quantification of effective polarisability. Applications to studies of X-ray photoelectron spectroscopy and alkylamine protonation" @default.
- W2047019898 doi "https://doi.org/10.1039/p29840000559" @default.
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