Matches in SemOpenAlex for { <https://semopenalex.org/work/W2047039353> ?p ?o ?g. }
- W2047039353 endingPage "13164" @default.
- W2047039353 startingPage "13155" @default.
- W2047039353 abstract "A modular approach to the total synthesis of furaquinocins culminated in the total syntheses of furaquinocin A, B, and E. A Pd-catalyzed dynamic kinetic asymmetric transformation (DYKAT) on carbonates derived from Baylis-Hillman adducts, followed by a reductive Heck cyclization allows the enantio- and diastereoselective construction of dihydrobenzofuran 32. Introduction of a double unsatured side chain via Horner-Wadsworth-Emmons reaction and assembly of the naphthoquinone with squaric acid based methodology leads to furaquinocin E. The use of differentially substituted squaric acid derivatives allows the synthesis of three analogues of furaquinocin E. The additional stereocenters in furaquinocin A and B can be introduced with a diastereoselective Sakurai allylation. The stereoselective elongation of the side chain is possible using cross metathesis or ring closing metathesis. The obtained late-stage intermediates were successfully transformed to furaquinocin A and B." @default.
- W2047039353 created "2016-06-24" @default.
- W2047039353 creator A5031747642 @default.
- W2047039353 creator A5032412691 @default.
- W2047039353 creator A5056094613 @default.
- W2047039353 date "2003-10-01" @default.
- W2047039353 modified "2023-10-03" @default.
- W2047039353 title "Total Syntheses of Furaquinocin A, B, and E" @default.
- W2047039353 cites W1969335186 @default.
- W2047039353 cites W1971101783 @default.
- W2047039353 cites W1975373576 @default.
- W2047039353 cites W1976355773 @default.
- W2047039353 cites W1977749745 @default.
- W2047039353 cites W1983600006 @default.
- W2047039353 cites W1984790756 @default.
- W2047039353 cites W1987624533 @default.
- W2047039353 cites W2001400219 @default.
- W2047039353 cites W2013790981 @default.
- W2047039353 cites W2018930310 @default.
- W2047039353 cites W2022974342 @default.
- W2047039353 cites W2024323261 @default.
- W2047039353 cites W2028201474 @default.
- W2047039353 cites W2028735827 @default.
- W2047039353 cites W2031004267 @default.
- W2047039353 cites W2031303273 @default.
- W2047039353 cites W2033267502 @default.
- W2047039353 cites W2033600634 @default.
- W2047039353 cites W2033727818 @default.
- W2047039353 cites W2041769371 @default.
- W2047039353 cites W2049772640 @default.
- W2047039353 cites W2050357401 @default.
- W2047039353 cites W2051538579 @default.
- W2047039353 cites W2052902938 @default.
- W2047039353 cites W2054686457 @default.
- W2047039353 cites W2060184492 @default.
- W2047039353 cites W2072063257 @default.
- W2047039353 cites W2074632092 @default.
- W2047039353 cites W2074797537 @default.
- W2047039353 cites W2081524589 @default.
- W2047039353 cites W2098166392 @default.
- W2047039353 cites W2107084423 @default.
- W2047039353 cites W2114311218 @default.
- W2047039353 cites W2122948038 @default.
- W2047039353 cites W2154385453 @default.
- W2047039353 cites W2176579084 @default.
- W2047039353 cites W2323974510 @default.
- W2047039353 cites W2949541685 @default.
- W2047039353 cites W2950034317 @default.
- W2047039353 cites W2951052808 @default.
- W2047039353 cites W2952474586 @default.
- W2047039353 cites W2952717383 @default.
- W2047039353 cites W2990312195 @default.
- W2047039353 cites W4241278884 @default.
- W2047039353 doi "https://doi.org/10.1021/ja0364118" @default.
- W2047039353 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/14570490" @default.
- W2047039353 hasPublicationYear "2003" @default.
- W2047039353 type Work @default.
- W2047039353 sameAs 2047039353 @default.
- W2047039353 citedByCount "144" @default.
- W2047039353 countsByYear W20470393532012 @default.
- W2047039353 countsByYear W20470393532013 @default.
- W2047039353 countsByYear W20470393532014 @default.
- W2047039353 countsByYear W20470393532015 @default.
- W2047039353 countsByYear W20470393532016 @default.
- W2047039353 countsByYear W20470393532017 @default.
- W2047039353 countsByYear W20470393532018 @default.
- W2047039353 countsByYear W20470393532019 @default.
- W2047039353 countsByYear W20470393532020 @default.
- W2047039353 countsByYear W20470393532021 @default.
- W2047039353 countsByYear W20470393532022 @default.
- W2047039353 countsByYear W20470393532023 @default.
- W2047039353 crossrefType "journal-article" @default.
- W2047039353 hasAuthorship W2047039353A5031747642 @default.
- W2047039353 hasAuthorship W2047039353A5032412691 @default.
- W2047039353 hasAuthorship W2047039353A5056094613 @default.
- W2047039353 hasConcept C134195300 @default.
- W2047039353 hasConcept C146686406 @default.
- W2047039353 hasConcept C153914509 @default.
- W2047039353 hasConcept C161790260 @default.
- W2047039353 hasConcept C178790620 @default.
- W2047039353 hasConcept C181647583 @default.
- W2047039353 hasConcept C185592680 @default.
- W2047039353 hasConcept C204921945 @default.
- W2047039353 hasConcept C21951064 @default.
- W2047039353 hasConcept C2778406045 @default.
- W2047039353 hasConcept C2778593322 @default.
- W2047039353 hasConcept C35753019 @default.
- W2047039353 hasConcept C44138296 @default.
- W2047039353 hasConcept C44228677 @default.
- W2047039353 hasConcept C521977710 @default.
- W2047039353 hasConcept C71240020 @default.
- W2047039353 hasConceptScore W2047039353C134195300 @default.
- W2047039353 hasConceptScore W2047039353C146686406 @default.
- W2047039353 hasConceptScore W2047039353C153914509 @default.
- W2047039353 hasConceptScore W2047039353C161790260 @default.
- W2047039353 hasConceptScore W2047039353C178790620 @default.
- W2047039353 hasConceptScore W2047039353C181647583 @default.
- W2047039353 hasConceptScore W2047039353C185592680 @default.