FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2047082322> ?p ?o ?g. }

• W2047082322 endingPage "112" @default.
• W2047082322 startingPage "103" @default.
• W2047082322 abstract "Halogen protected CMPO derivatives of the cobalt bis(dicarbollide) ion (1−) were synthesized with the aim to develop efficient extraction agents with increased stability for liquid–liquid extraction of lanthanides and actinides from high-level activity nuclear waste. New halogen protected compounds of the general formulation [3,3′-Co(III)-(8-CMPO-(CH2-CH2O)2-1,2-C2B9H10)(8′-X-1′,2′-C2B9H10)]− (where X = Cl, Br, I; CMPO = Ph2P(O)-CH2C(O)(t-C8H17)N-) (4a–c), were prepared and studied for Ln(III)/An(III) group extraction. These compounds were accessible via halogenated zwitterionic amino derivatives [3,3′-Co(III)-(8-t-C8H17NH2-(CH2-CH2O)2-1,2-C2B9H10)(8′-X-1′,2′-C2B9H10)] (3a–c), prepared by several different synthetic methods. All the compounds were characterized by a combination of 11B NMR, 1H high field NMR, ESI-MS, HPLC and other methods. The effect of the halogen in the structures of 4a–c on the extraction properties is outlined. In general, these compounds preserve good extraction efficiency and exhibit a better stability. On the other hand, the character of the halogenated ion 1− seems to prevail in these compounds and their best extraction efficiency was achieved in more polar auxiliary solvents such as nitro-, chloro-solvents or a laurylonitrile–dodecane mixture than in mixtures of hexyl methyl ketone (HMK) and dodecane (D) applied as the optimum solution for extraction with the parent compound 4, which contains no halogen in the structure. The reason for this behaviour can be seen in the substitution of the polarized B(8′)–Hδ− bond, which may contribute to complexation or protonation at the B(8)–O-site, smoothing thus the solubility of 4 in low polar solvents." @default.
• W2047082322 created "2016-06-24" @default.
• W2047082322 creator A5017916542 @default.
• W2047082322 creator A5025879573 @default.
• W2047082322 creator A5043217643 @default.
• W2047082322 creator A5051651299 @default.
• W2047082322 date "2012-05-01" @default.
• W2047082322 modified "2023-09-25" @default.
• W2047082322 title "Halogen protected cobalt bis(dicarbollide) ions with covalently bonded CMPO functions as anionic extractants for trivalent lanthanide/actinide partitioning" @default.
• W2047082322 cites W1942804016 @default.
• W2047082322 cites W1972385707 @default.
• W2047082322 cites W1972949109 @default.
• W2047082322 cites W1976183340 @default.
• W2047082322 cites W1979685069 @default.
• W2047082322 cites W1988647696 @default.
• W2047082322 cites W1989143510 @default.
• W2047082322 cites W1995040131 @default.
• W2047082322 cites W2005203290 @default.
• W2047082322 cites W2008150552 @default.
• W2047082322 cites W2009742901 @default.
• W2047082322 cites W2021906264 @default.
• W2047082322 cites W2022073883 @default.
• W2047082322 cites W2023590857 @default.
• W2047082322 cites W2028748121 @default.
• W2047082322 cites W2037839860 @default.
• W2047082322 cites W2039348143 @default.
• W2047082322 cites W2042242372 @default.
• W2047082322 cites W2042275198 @default.
• W2047082322 cites W2043900341 @default.
• W2047082322 cites W2046768801 @default.
• W2047082322 cites W2048687688 @default.
• W2047082322 cites W2049826696 @default.
• W2047082322 cites W2050309854 @default.
• W2047082322 cites W2051649380 @default.
• W2047082322 cites W2052690966 @default.
• W2047082322 cites W2063340460 @default.
• W2047082322 cites W2064726828 @default.
• W2047082322 cites W2075028948 @default.
• W2047082322 cites W2081245444 @default.
• W2047082322 cites W2081588323 @default.
• W2047082322 cites W2087241300 @default.
• W2047082322 cites W2088942255 @default.
• W2047082322 cites W2094116366 @default.
• W2047082322 cites W2118611913 @default.
• W2047082322 cites W2138239793 @default.
• W2047082322 cites W2141025463 @default.
• W2047082322 cites W2161018367 @default.
• W2047082322 cites W2171914066 @default.
• W2047082322 cites W2323516673 @default.
• W2047082322 cites W2340273043 @default.
• W2047082322 cites W4229772442 @default.
• W2047082322 doi "https://doi.org/10.1016/j.poly.2012.02.029" @default.
• W2047082322 hasPublicationYear "2012" @default.
• W2047082322 type Work @default.
• W2047082322 sameAs 2047082322 @default.
• W2047082322 citedByCount "13" @default.
• W2047082322 countsByYear W20470823222013 @default.
• W2047082322 countsByYear W20470823222014 @default.
• W2047082322 countsByYear W20470823222015 @default.
• W2047082322 countsByYear W20470823222016 @default.
• W2047082322 countsByYear W20470823222017 @default.
• W2047082322 countsByYear W20470823222022 @default.
• W2047082322 crossrefType "journal-article" @default.
• W2047082322 hasAuthorship W2047082322A5017916542 @default.
• W2047082322 hasAuthorship W2047082322A5025879573 @default.
• W2047082322 hasAuthorship W2047082322A5043217643 @default.
• W2047082322 hasAuthorship W2047082322A5051651299 @default.
• W2047082322 hasConcept C135788738 @default.
• W2047082322 hasConcept C13965031 @default.
• W2047082322 hasConcept C145148216 @default.
• W2047082322 hasConcept C155647269 @default.
• W2047082322 hasConcept C178790620 @default.
• W2047082322 hasConcept C179104552 @default.
• W2047082322 hasConcept C185592680 @default.
• W2047082322 hasConcept C201770740 @default.
• W2047082322 hasConcept C2777738585 @default.
• W2047082322 hasConcept C2780263894 @default.
• W2047082322 hasConcept C46062151 @default.
• W2047082322 hasConcept C4725764 @default.
• W2047082322 hasConcept C515602321 @default.
• W2047082322 hasConceptScore W2047082322C135788738 @default.
• W2047082322 hasConceptScore W2047082322C13965031 @default.
• W2047082322 hasConceptScore W2047082322C145148216 @default.
• W2047082322 hasConceptScore W2047082322C155647269 @default.
• W2047082322 hasConceptScore W2047082322C178790620 @default.
• W2047082322 hasConceptScore W2047082322C179104552 @default.
• W2047082322 hasConceptScore W2047082322C185592680 @default.
• W2047082322 hasConceptScore W2047082322C201770740 @default.
• W2047082322 hasConceptScore W2047082322C2777738585 @default.
• W2047082322 hasConceptScore W2047082322C2780263894 @default.
• W2047082322 hasConceptScore W2047082322C46062151 @default.
• W2047082322 hasConceptScore W2047082322C4725764 @default.
• W2047082322 hasConceptScore W2047082322C515602321 @default.
• W2047082322 hasFunder F4320321005 @default.
• W2047082322 hasFunder F4320321006 @default.
• W2047082322 hasIssue "1" @default.
• W2047082322 hasLocation W20470823221 @default.
• W2047082322 hasOpenAccess W2047082322 @default.

• next