FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2047195899> ?p ?o ?g. }

• W2047195899 endingPage "200" @default.
• W2047195899 startingPage "191" @default.
• W2047195899 abstract "Framework-substituted, molecular-sieve, aluminophosphate, microporous solids are the centerpieces of a new approach to the aerobic oxyfunctionalization of saturated hydrocarbons. The sieves, and the few percent of the Al(III) sites within them that are replaced by catalytically active, transition-metal ions in high oxidation states (Co(III), Mn(III), Fe(III)), are designed so as to allow free access of oxygen in to and out of the interior of these high-area solids. Certain metal-substituted, molecular sieves permit only end-on approach of linear alkanes to the active centers, thereby favoring enhanced reactivity of the terminal methyl groups. By optimizing cage dimension, with respect to that of the hydrocarbon reactant, as well as adjusting the average separation of active centers within a cage, and by choosing the sieve with the appropriate pore aperture, highly selective conversions such as n-hexane to hexanoic acid or adipic acid, and cyclohexane to cyclohexanol, cyclohexanone, or adipic acid, may be effected at low temperature, heterogeneously in air." @default.
• W2047195899 created "2016-06-24" @default.
• W2047195899 creator A5021578053 @default.
• W2047195899 creator A5033087518 @default.
• W2047195899 creator A5050610079 @default.
• W2047195899 creator A5086196263 @default.
• W2047195899 date "2001-01-25" @default.
• W2047195899 modified "2023-10-14" @default.
• W2047195899 title "Molecular Sieve Catalysts for the Regioselective and Shape- Selective Oxyfunctionalization of Alkanes in Air" @default.
• W2047195899 cites W145426915 @default.
• W2047195899 cites W1493703385 @default.
• W2047195899 cites W1521206570 @default.
• W2047195899 cites W1533273652 @default.
• W2047195899 cites W1610417854 @default.
• W2047195899 cites W1891675164 @default.
• W2047195899 cites W1969835063 @default.
• W2047195899 cites W1983164604 @default.
• W2047195899 cites W1987594336 @default.
• W2047195899 cites W1990700494 @default.
• W2047195899 cites W1998539539 @default.
• W2047195899 cites W2013393709 @default.
• W2047195899 cites W2014244446 @default.
• W2047195899 cites W2016948034 @default.
• W2047195899 cites W2023558950 @default.
• W2047195899 cites W2029889304 @default.
• W2047195899 cites W2031996439 @default.
• W2047195899 cites W2034672440 @default.
• W2047195899 cites W2035098372 @default.
• W2047195899 cites W2037449384 @default.
• W2047195899 cites W2038638766 @default.
• W2047195899 cites W2044558903 @default.
• W2047195899 cites W2045444647 @default.
• W2047195899 cites W2046519320 @default.
• W2047195899 cites W2070616224 @default.
• W2047195899 cites W2074354774 @default.
• W2047195899 cites W2074830122 @default.
• W2047195899 cites W2079424762 @default.
• W2047195899 cites W2083212924 @default.
• W2047195899 cites W2083925064 @default.
• W2047195899 cites W2086259494 @default.
• W2047195899 cites W2091629083 @default.
• W2047195899 cites W2095325222 @default.
• W2047195899 cites W2096130077 @default.
• W2047195899 cites W2100433311 @default.
• W2047195899 cites W2115913534 @default.
• W2047195899 cites W2119994537 @default.
• W2047195899 cites W2134297174 @default.
• W2047195899 cites W2135098829 @default.
• W2047195899 cites W2143347142 @default.
• W2047195899 cites W2143521521 @default.
• W2047195899 cites W2163818729 @default.
• W2047195899 cites W2170429301 @default.
• W2047195899 cites W2949373928 @default.
• W2047195899 cites W2949472716 @default.
• W2047195899 cites W2952535426 @default.
• W2047195899 cites W2952701260 @default.
• W2047195899 cites W3004956568 @default.
• W2047195899 cites W99668487 @default.
• W2047195899 doi "https://doi.org/10.1021/ar970020e" @default.
• W2047195899 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11263877" @default.
• W2047195899 hasPublicationYear "2001" @default.
• W2047195899 type Work @default.
• W2047195899 sameAs 2047195899 @default.
• W2047195899 citedByCount "280" @default.
• W2047195899 countsByYear W20471958992012 @default.
• W2047195899 countsByYear W20471958992013 @default.
• W2047195899 countsByYear W20471958992014 @default.
• W2047195899 countsByYear W20471958992015 @default.
• W2047195899 countsByYear W20471958992016 @default.
• W2047195899 countsByYear W20471958992017 @default.
• W2047195899 countsByYear W20471958992018 @default.
• W2047195899 countsByYear W20471958992019 @default.
• W2047195899 countsByYear W20471958992021 @default.
• W2047195899 countsByYear W20471958992022 @default.
• W2047195899 countsByYear W20471958992023 @default.
• W2047195899 crossrefType "journal-article" @default.
• W2047195899 hasAuthorship W2047195899A5021578053 @default.
• W2047195899 hasAuthorship W2047195899A5033087518 @default.
• W2047195899 hasAuthorship W2047195899A5050610079 @default.
• W2047195899 hasAuthorship W2047195899A5086196263 @default.
• W2047195899 hasConcept C105281773 @default.
• W2047195899 hasConcept C106773901 @default.
• W2047195899 hasConcept C142724271 @default.
• W2047195899 hasConcept C161790260 @default.
• W2047195899 hasConcept C178790620 @default.
• W2047195899 hasConcept C179104552 @default.
• W2047195899 hasConcept C185592680 @default.
• W2047195899 hasConcept C204787440 @default.
• W2047195899 hasConcept C2776230335 @default.
• W2047195899 hasConcept C2776606100 @default.
• W2047195899 hasConcept C2776910235 @default.
• W2047195899 hasConcept C2777207669 @default.
• W2047195899 hasConcept C2778237882 @default.
• W2047195899 hasConcept C2780450521 @default.
• W2047195899 hasConcept C71924100 @default.
• W2047195899 hasConcept C86381522 @default.
• W2047195899 hasConceptScore W2047195899C105281773 @default.
• W2047195899 hasConceptScore W2047195899C106773901 @default.

• next