Matches in SemOpenAlex for { <https://semopenalex.org/work/W2047199377> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W2047199377 endingPage "L373" @default.
- W2047199377 startingPage "L369" @default.
- W2047199377 abstract "Redox flow batteries are a promising technology for large scale energy storage systems. Although some types of the battery have been commercialized, the narrow working voltage ranges in the aqueous electrolytes limit their further applications. Organic solvents have shown to allow the use of a wider range of redox couples and the idea of non-aqueous redox flow batteries has been proposed. However, the low solubilities and poor electrochemical properties including stability and reversibility of the redox couples in the organic electrolytes remain a significant issue. In this work, a series of heteroleptic (mixed ligand) iron(II) complexes based on a combination of 2,2′-bipyridine, 1,10-phenanthroline and 4,4′-dimethyl-2,2′-bipyridine ligands were synthesized and their chemical and electrochemical properties investigated. For Fe (II) complexes, it was confirmed that ligand equilibration occurs in solution. The electrochemical properties of the complexes were studied by cyclic voltammogram and chronoamperometric methods. The mechanism of the redox processes of these complexes are proposed and how the mixed ligands will affect the redox potentials of the Fe (II) complexes is discussed. Furthermore, we show that the mixed ligand system can improve the total solubility of redox active species. The mixed ligand approach will also be beneficial for designing other new high solubility redox materials for non- aqueous flow batteries." @default.
- W2047199377 created "2016-06-24" @default.
- W2047199377 creator A5037462713 @default.
- W2047199377 creator A5058890009 @default.
- W2047199377 creator A5075659230 @default.
- W2047199377 date "1979-01-01" @default.
- W2047199377 modified "2023-10-16" @default.
- W2047199377 title "Further studies on the stabilization of high and low oxidation states in aromatic imine ligand complexes of first row transition metals. I. Substituted bipyridine complexes of cobalt and iron" @default.
- W2047199377 cites W1480445900 @default.
- W2047199377 cites W1524975913 @default.
- W2047199377 cites W1967526359 @default.
- W2047199377 cites W1999173334 @default.
- W2047199377 cites W2007690217 @default.
- W2047199377 cites W2025456770 @default.
- W2047199377 cites W2027769780 @default.
- W2047199377 cites W2032782284 @default.
- W2047199377 cites W2067609634 @default.
- W2047199377 cites W2073622329 @default.
- W2047199377 cites W2119354424 @default.
- W2047199377 cites W2908750684 @default.
- W2047199377 cites W2910467781 @default.
- W2047199377 doi "https://doi.org/10.1016/s0020-1693(00)93402-9" @default.
- W2047199377 hasPublicationYear "1979" @default.
- W2047199377 type Work @default.
- W2047199377 sameAs 2047199377 @default.
- W2047199377 citedByCount "22" @default.
- W2047199377 countsByYear W20471993772012 @default.
- W2047199377 countsByYear W20471993772014 @default.
- W2047199377 countsByYear W20471993772015 @default.
- W2047199377 countsByYear W20471993772019 @default.
- W2047199377 countsByYear W20471993772020 @default.
- W2047199377 crossrefType "journal-article" @default.
- W2047199377 hasAuthorship W2047199377A5037462713 @default.
- W2047199377 hasAuthorship W2047199377A5058890009 @default.
- W2047199377 hasAuthorship W2047199377A5075659230 @default.
- W2047199377 hasConcept C115624301 @default.
- W2047199377 hasConcept C116569031 @default.
- W2047199377 hasConcept C147789679 @default.
- W2047199377 hasConcept C155574463 @default.
- W2047199377 hasConcept C161790260 @default.
- W2047199377 hasConcept C170493617 @default.
- W2047199377 hasConcept C17525397 @default.
- W2047199377 hasConcept C178790620 @default.
- W2047199377 hasConcept C179104552 @default.
- W2047199377 hasConcept C184651966 @default.
- W2047199377 hasConcept C185592680 @default.
- W2047199377 hasConcept C21951064 @default.
- W2047199377 hasConcept C2776573223 @default.
- W2047199377 hasConcept C2777596839 @default.
- W2047199377 hasConcept C2779336533 @default.
- W2047199377 hasConcept C52859227 @default.
- W2047199377 hasConcept C55493867 @default.
- W2047199377 hasConcept C55904794 @default.
- W2047199377 hasConcept C68801617 @default.
- W2047199377 hasConcept C89477785 @default.
- W2047199377 hasConceptScore W2047199377C115624301 @default.
- W2047199377 hasConceptScore W2047199377C116569031 @default.
- W2047199377 hasConceptScore W2047199377C147789679 @default.
- W2047199377 hasConceptScore W2047199377C155574463 @default.
- W2047199377 hasConceptScore W2047199377C161790260 @default.
- W2047199377 hasConceptScore W2047199377C170493617 @default.
- W2047199377 hasConceptScore W2047199377C17525397 @default.
- W2047199377 hasConceptScore W2047199377C178790620 @default.
- W2047199377 hasConceptScore W2047199377C179104552 @default.
- W2047199377 hasConceptScore W2047199377C184651966 @default.
- W2047199377 hasConceptScore W2047199377C185592680 @default.
- W2047199377 hasConceptScore W2047199377C21951064 @default.
- W2047199377 hasConceptScore W2047199377C2776573223 @default.
- W2047199377 hasConceptScore W2047199377C2777596839 @default.
- W2047199377 hasConceptScore W2047199377C2779336533 @default.
- W2047199377 hasConceptScore W2047199377C52859227 @default.
- W2047199377 hasConceptScore W2047199377C55493867 @default.
- W2047199377 hasConceptScore W2047199377C55904794 @default.
- W2047199377 hasConceptScore W2047199377C68801617 @default.
- W2047199377 hasConceptScore W2047199377C89477785 @default.
- W2047199377 hasLocation W20471993771 @default.
- W2047199377 hasOpenAccess W2047199377 @default.
- W2047199377 hasPrimaryLocation W20471993771 @default.
- W2047199377 hasRelatedWork W2047199377 @default.
- W2047199377 hasRelatedWork W2373948789 @default.
- W2047199377 hasRelatedWork W2382239929 @default.
- W2047199377 hasRelatedWork W2752822941 @default.
- W2047199377 hasRelatedWork W2896656398 @default.
- W2047199377 hasRelatedWork W2949187813 @default.
- W2047199377 hasRelatedWork W3137463126 @default.
- W2047199377 hasRelatedWork W3143660937 @default.
- W2047199377 hasRelatedWork W4309509384 @default.
- W2047199377 hasRelatedWork W4313593394 @default.
- W2047199377 hasVolume "35" @default.
- W2047199377 isParatext "false" @default.
- W2047199377 isRetracted "false" @default.
- W2047199377 magId "2047199377" @default.
- W2047199377 workType "article" @default.