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- W2047201634 abstract "Abstract The adsorption of various alkylammonium cations was investigated by measurement of the interfacial tension. Tetraethanolammonium ions (HOC2H4)4N+ showed weaker adsorbability than that expected from its ionic radius. The adsorbabilities (relative surface excess of cation FΓ+ and charge of specifically adsorbed cation q1+) of the ethyl series (C2H5)nH4−nN+(n = 0 ≈ 4), and of the methyl series (CH3)nH4−nN+n = 0 ≈ 3) were directly proportional to the hydration enthalpies of these cations - ΔH0h, but the proportionalities were different between the methyl and the ethyl series. A linear relation was, however, found between FΓ+ and the hydration entropies - ΔS0h without regard to the kinds of cations. A similar relation was also found between q1+− - ΔS0h. In conclusion, the adsorbabilities of these cations were governed by the hydration entropy, not by the hydration enthalpy." @default.
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- W2047201634 date "1976-07-01" @default.
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- W2047201634 title "An effect of hydration entropy on adsorption of various alkylammonium ions at the mercury/water interface" @default.
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- W2047201634 doi "https://doi.org/10.1016/0013-4686(76)85142-0" @default.
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