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- W2047202152 abstract "An off-line coupling of size-exclusion chromatography (SEC) and thermal field-flow fractionation (ThFFF) was used successfully to cross-fractionate copolymers and polymer blends. Various fractions of different molecular mass were obtained from polydisperse polymer samples by SEC. Because the molecular diffusion coefficients were known, the ThFFF analysis of these fractions yielded directly thermal diffusion coefficients. As thermal diffusion is strongly affected by the chemical nature of the polymer, the chemical composition of polymer samples can be studied as function of the molecular mass with this technique. This is illustrated with the SEC-ThFFF cross-fractionation of a polystyrene sample blended with a polybutadiene and a polytetrahydrofuran standard, and of butadiene- and styrene-methylmethacrylate copolymers." @default.
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- W2047202152 date "1995-06-01" @default.
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- W2047202152 title "Determination of the compositional heterogeneity of polydisperse polymer samples by the coupling of size-exclusion chromatography and thermal field-flow fractionation" @default.
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- W2047202152 doi "https://doi.org/10.1016/0021-9673(94)01165-b" @default.
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