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• W2047240638 abstract "The phase diagrams of the ZrO2–CaO, ZrO2–Y2O3, ThO2–Y2O3 and ThO2–La2O3 systems are discussed in view of the use of the electrolytes in emf measurements. It is shown that thermodynamic studies on metallic A-B systems using solid galvanic cells with oxygen and fluorine ion conducting electrolytes require the knowledge of the phase diagrams of the corresponding ternary A-B-O and A-B-F systems for the cell arrangements. Examples for misleading emf measurements by use of incompatible electrodes are given. Asymmetric cells, side reactions between the electrodes and the electrical leads, and impurities in the cover gas as sources for erroneous emf measurements are demonstrated. The characteristics of reference electrodes for oxide electrolytes in environments with different oxygen partial pressures are outlined. The role of oxygen as an impurity in the electrodes for CaF2 electrolytes is investigated." @default.
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• W2047240638 date "1983-09-01" @default.
• W2047240638 modified "2023-09-27" @default.
• W2047240638 title "Experimental Aspects of Solid Galvanic Cell Methods for Thermodynamic Studies on Alloys" @default.
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• W2047240638 doi "https://doi.org/10.1002/bbpc.19830870911" @default.
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