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- W2047284397 abstract "In 6 n H2SO4 aufgenommene Strom-Spannung-Kurven zeigen bei −0,45V das Entstehen einer Passivschicht aus Ti-Hydrid und Ti-O (Sauerstoffgehalt 0 bis 1,0). In den anschließenden 200mV wandelt sich diese Schicht um in eine Passivschicht, die n-leitend ist und aus TiO2 mit etwas Ti3O5 besteht. In NaOH (1,0 n, 6,0 n) entsteht ab −0,614 V eine ausschließlich aus TiO2 bestehende Schicht, ab 1,8 V tritt Sauerstoffentwicklung auf. Die Einstellung des Ruhepotentials erfordert ziemlich lange Zeit abhängig von Oberflächenzustand und Feuchtigkeitsgehalt der Elektrode. The electrochemical behaviour of titanium Current-potential curves established in 6 N sulfuric acid show at −0,45 V the formation of a passive layer of titanium hydride and Ti-O (oxygen content 0 to 1.0). In the subsequent range of 200 mV this layer is converted into a passive layer of the n-conductor and which consists of TiO2 with a little Ti3O5. In NaOH (1.0 and 6.0 N) a layer consisting exclusively of TiO2 is formed above −0.614 V, and above 1.8 V there is evolution of oxygen. The results are interpreted in terms of thermodynamics. The rest potential requires considerable time for reaching its stationary value, depending on the state of the surface and the moisture content of the electrode." @default.
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- W2047284397 date "1969-08-01" @default.
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- W2047284397 title "Das elektrochemische Verhalten von Titan" @default.
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- W2047284397 doi "https://doi.org/10.1002/maco.19690200806" @default.
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