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• W2047360327 abstract "Abstract Under very mild reaction conditions, iron or copper nanoparticles efficiently promoted the homocoupling of different Grignard reagents in tetrahydrofuran at room temperature. The nanosized iron or copper particles were generated in situ in a simple and economical way from commercially available FeCl2 or CuCl2, respectively, an excess of lithium powder, and a catalytic amount (5 mol%) of 4,4′-di-tert-butylbiphenyl (DTBB) as electron carrier. The reaction of a series of aryl, heteroaryl, benzyl, and alkenyl Grignard reagents in the presence of a substoichiometric amount of the iron or copper nanoparticles led to the formation of the corresponding homocoupling products in good yield." @default.
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• W2047360327 date "2008-10-20" @default.
• W2047360327 modified "2023-09-26" @default.
• W2047360327 title "Nanosized Iron- or Copper-Catalyzed Homocoupling of Aryl, Heteroaryl, Benzyl, and Alkenyl Grignard Reagents" @default.
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• W2047360327 doi "https://doi.org/10.1080/00397910802238726" @default.
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