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• W2047417053 abstract "The UV (254 nm) and UV/VUV (254/185 nm) photolysis of phenol and the distribution of the products in solutions saturated with oxygen or nitrogen were investigated and compared. The initial rate of degradation of phenol in UV/VUV-irradiated solutions exceeded that determined in UV-irradiated solutions, but the difference decreased dramatically with increase of the initial phenol concentration. The effects of methanol as HO scavenger demonstrated that the relative contribution of the HO-based reactions to the decomposition of phenol in UV/VUV-irradiated solutions decreased strongly with increase of the initial phenol concentration. The same aromatic (1,2- and 1,4-dihydroxybenzene) and aliphatic (maleic, malic, tartaric and oxalic acids) intermediates were detected in UV- and UV/VUV-irradiated solutions saturated with oxygen. The decompositions of 1,2- and 1,4-dihydroxybenzene, 1,4-benzoquinone and oxalic acid were also investigated both in UV/VUV- and in UV-irradiated solutions." @default.
• W2047417053 created "2016-06-24" @default.
• W2047417053 creator A5006340854 @default.
• W2047417053 creator A5013346352 @default.
• W2047417053 date "2007-05-01" @default.
• W2047417053 modified "2023-09-30" @default.
• W2047417053 title "Comparative study of the UV and UV/VUV-induced photolysis of phenol in aqueous solution" @default.
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• W2047417053 doi "https://doi.org/10.1016/j.jphotochem.2007.01.002" @default.
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