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- W2047449852 abstract "Eine sehr kurze Synthese angesichts der Struktur: (−)-Lepadiformin (−)-3 wurde mit einer Gesamtausbeute von 31.4 % in nur neun Stufen synthetisiert. Der Schlüsselschritt war die Bildung von 2 durch Spirocyclisierung des aus 1 erzeugten N-Acyliminiumions. Darüber hinaus konnte auch die absolute Konfiguration von 3 ermittelt werden (3S,5R,7aS,11aS). Bn=Benzyl, Boc=tert-Butoxycarbonyl." @default.
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- W2047449852 date "2002-08-16" @default.
- W2047449852 modified "2023-10-17" @default.
- W2047449852 title "Total Synthesis of the Natural Enantiomer of (â)-Lepadiformine and Determination of Its Absolute Stereochemistry This work was supported in part by a Grant for Private Universities provided by the Ministry of Education, Sports, and Culture of Japan and the Promotion and Mutual Aid Corporation for Private Schools of Japan. We are grateful to Professor J. F. Biard for a sample of natural lepadiformine." @default.
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