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- W2047482333 abstract "The conductivity of the potassium salts of carboxymethylcellulose (CMC) and poly-p-styrene sulfonate (PSS) in the presence of KCl shows a behavior which is in striking contrast to the results of a previously developed theory: when the total concentration of K plus Cl ions is kept constant, the conductivity decreases with increasing polymer content in the majority of cases. Qualitatively this can be explained by a theory of the relaxation effect. This theory makes use of the model of a porous sphere in which the counter ions completely compensate the charge of the fixed ions. The use of the Debye-Huckel approximation is avoided. The charge resulting from relaxation effects is treated as a surface charge." @default.
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- W2047482333 date "1957-10-01" @default.
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- W2047482333 title "Conductivity of solutions of the potassium salts of carboxymethylcellulose and sulfonated polystyrene in the presence of potassium chloride" @default.
- W2047482333 doi "https://doi.org/10.1002/pol.1957.1202611205" @default.
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